On the local mode behaviour of the XH2/XD2 and XD/XH fragments with respect to the deuterated species of the near local mode XH3(C3v ) molecule / O. N. Ulenikov, E. S. Bekhtereva, C. Leroy

Уровень набора: Molecular Physics, An International Journal at the Interface Between Chemistry and PhysicsОсновной Автор-лицо: Ulenekov (Ulenikov), O. N., physicist, Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, 1949-, Oleg NikolaevichАльтернативный автор-лицо: Bekhtereva, E. S., physicist, Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, 1974-, Elena Sergeevna;Leroy, K. A., physicist, Junior researcher at Tomsk Polytechnic University, candidate of physico-mathematical Sciences, Professor, University of Montreal (France), 1961-, Klod (Claude) AndreЯзык: английский.Страна: .Резюме или реферат: Effect of isotopic substitution in the near local mode, XH3(C3v ), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3(C3v ) molecule with the value of interbond angle close to п/2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode ‘molecule’ XH2/XD2 and of a diatomic XD/XH ‘molecule’. The phosphine molecule is considered as an illustration..Примечания о наличии в документе библиографии/указателя: [References: p. 1415 (15 tit.)].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: p. 1415 (15 tit.)]

Effect of isotopic substitution in the near local mode, XH3(C3v ), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3(C3v ) molecule with the value of interbond angle close to п/2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode ‘molecule’ XH2/XD2 and of a diatomic XD/XH ‘molecule’. The phosphine molecule is considered as an illustration.

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