Investigation of the preparation and catalytic activity of supported Mo, W, and Re oxides as heterogeneous catalysts in olefin metathesis / N. Gholampour, M. S. Yusubov, F. V. K. Verpoort

Уровень набора: Catalysis Reviews-Science and Engineering = 1986-Основной Автор-лицо: Gholampour, N., NadiaАльтернативный автор-лицо: Yusubov, M. S., chemist, Professor of Tomsk Polytechnic University, Doctor of chemical sciences, 1961-, Mekhman Suleiman-Ogly (Suleimanovich);Verpoort, F. V. K., Chemical Engineer, Professor of Tomsk Polytechnic University, doctor of chemical Sciences, 1963-, Frensis Valter KorneliusКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет (ТПУ), Институт природных ресурсов (ИПР), Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)Язык: английский.Страна: .Резюме или реферат: For several decades olefin metathesis reactions over supported Mo, W, and Re oxides catalysts have attracted remarkable interest owning to their growing industrial applications. Therefore, particular attention was devoted to improve the catalytic activity of these catalysts. In the way of exploration of the catalytic performances of these heterogeneous Mo, W, and Re oxides systems, it was found that high dispersion of metal oxide on the support surface and the oxidation state of the metal oxide on the surface of catalyst play crucial factors on the catalysts efficiency. Importantly, these factors have an origin in the preparation methods and the properties of the used supports. In this regard, we have tried to address the various preparation methods of immobilized Mo, W, and Re oxide catalysts as well as properties of supporting material to better understand their impacts on the catalytic performances of these catalysts..Примечания о наличии в документе библиографии/указателя: [References: 186 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | кислотность | иммобилизация Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: 186 tit.]

For several decades olefin metathesis reactions over supported Mo, W, and Re oxides catalysts have attracted remarkable interest owning to their growing industrial applications. Therefore, particular attention was devoted to improve the catalytic activity of these catalysts. In the way of exploration of the catalytic performances of these heterogeneous Mo, W, and Re oxides systems, it was found that high dispersion of metal oxide on the support surface and the oxidation state of the metal oxide on the surface of catalyst play crucial factors on the catalysts efficiency. Importantly, these factors have an origin in the preparation methods and the properties of the used supports. In this regard, we have tried to address the various preparation methods of immobilized Mo, W, and Re oxide catalysts as well as properties of supporting material to better understand their impacts on the catalytic performances of these catalysts.

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