An integrated criterion of efficiency for Pt catalysts in the dehydrogenation of higher n-paraffins / R. V. Romanovskiy [et al.]

Уровень набора: Catalysis in Industry, Scientific JournalАльтернативный автор-лицо: Romanovskiy, R. V., Chemical Engineer, Engineer of Tomsk Polytechnic University, 1987-, Rostislav Vladimirovich;Frantsina, E. V., Chemical Engineer, Associate Professor of Tomsk Polytechnic University, Candidate of technical sciences, 1985-, Evgeniya Vladimirovna;Youriev, Е. M.;Ivashkina, E. N., Chemical Engineer, Associate Professor of Tomsk Polytechnic University, Candidate of technical science, 1983-, Elena Nikolaevna;Ivanchina, E. D., chemist, Professor of Tomsk Polytechnic University, Doctor of technical sciences, 1951-, Emilia Dmitrievna;Kravtsov, A. V., Chemical Engineer, Consulting Professor, Doctor of Technical Sciences (DSc), 1938-2012, Anatoly VasilyevichЯзык: английский.Резюме или реферат: The deactivation of catalysts by coke-forming structures in the dehydrogenation of higher n-paraffins is discussed. The patterns of coke formation on a catalyst subject to process conditions are presented. A mathematical model of the process is described to show its adequacy. A calculation algorithm for the optimum mode of operation of a dehydrogenation catalyst is constructed, and the calculation results are given. Dehydrogenation catalysts of different brands are compared with respect to several parameters (coke formation on catalysts, the yield of the reaction by-product, and the dynamics of temperature rise in the reactor). The model can be used to estimate the efficiencies of catalysts in a cycle and to compare them..Примечания о наличии в документе библиографии/указателя: [Ref.: p. 367 (3 tit.)].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | катализаторы | дегидрирование | алканы | методы | платина Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[Ref.: p. 367 (3 tit.)]

The deactivation of catalysts by coke-forming structures in the dehydrogenation of higher n-paraffins is discussed. The patterns of coke formation on a catalyst subject to process conditions are presented. A mathematical model of the process is described to show its adequacy. A calculation algorithm for the optimum mode of operation of a dehydrogenation catalyst is constructed, and the calculation results are given. Dehydrogenation catalysts of different brands are compared with respect to several parameters (coke formation on catalysts, the yield of the reaction by-product, and the dynamics of temperature rise in the reactor). The model can be used to estimate the efficiencies of catalysts in a cycle and to compare them.

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