Corrosion Resistance of Neodymium and Dysprosium Hydrides / N. Karakchieva [et al.]

Уровень набора: (RuTPU)RU\TPU\network\4816, AIP Conference ProceedingsАльтернативный автор-лицо: Karakchieva, N., Natalia;Lyamina, G. V., chemist, Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences, 1974-, Galina Vladimirovna;Knyazeva, E. M., chemist, Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences, 1956-, Elena Mikhailovna;Sachkov, V., Victor;Kurzina, I., Irina;Pichugina, A., Alina;Vladimirov, A., Alexander;Kazantseva, L., Ludmila;Sachkova, A. S., biologist, Associate Professor of Tomsk Polytechnic University, candidate of biological sciences, 1986-, Anna SergeevnaКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет, Инженерная школа новых производственных технологий, Отделение материаловедения;Национальный исследовательский Томский политехнический университет, Школа базовой инженерной подготовки, Отделение естественных наук;Национальный исследовательский Томский политехнический университет, Инженерная школа ядерных технологий, Отделение ядерно-топливного циклаЯзык: английский.Серия: Modification of materials structure and propertiesРезюме или реферат: This paper describes the methods of obtaining hydrides of rare earth elements such as dysprosium and neodymium. The properties and corrosion resistance of these elements are investigated. A synthesis method of monophasic dysprosium and neodymium dihydrides is presented. Synthesized dihydrides are agglomerates with an average size of 3-50 [mu]m and are formed by crystalline grains of a nanometer size. BET specific surface area, morphology, elemental analyses and composition of samples have been studied. Corrosion stability in aqueous solutions of hydrochloric acid and sodium hydroxide were studied. It was determined that both hydrides undergo hydrolysis in acid and alkaline mediums. Neodymium hydride is more stable to corrosion than dysprosium hydride, which is proved by its longer exposure to aggressive medium to hydrides. The formation of insoluble /poorly soluble products of corrosion can make a significant contribution to the process of powder dissolution..Примечания о наличии в документе библиографии/указателя: [References: 16 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | коррозионная стойкость | диспрозий | редкоземельные элементы | неодим | растворение | порошки Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: 16 tit.]

This paper describes the methods of obtaining hydrides of rare earth elements such as dysprosium and neodymium. The properties and corrosion resistance of these elements are investigated. A synthesis method of monophasic dysprosium and neodymium dihydrides is presented. Synthesized dihydrides are agglomerates with an average size of 3-50 [mu]m and are formed by crystalline grains of a nanometer size. BET specific surface area, morphology, elemental analyses and composition of samples have been studied. Corrosion stability in aqueous solutions of hydrochloric acid and sodium hydroxide were studied. It was determined that both hydrides undergo hydrolysis in acid and alkaline mediums. Neodymium hydride is more stable to corrosion than dysprosium hydride, which is proved by its longer exposure to aggressive medium to hydrides. The formation of insoluble /poorly soluble products of corrosion can make a significant contribution to the process of powder dissolution.

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