Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis / S. Uraoka, I. Shinohara, H. Shimizu [et al.]
Уровень набора: European Journal of Organic ChemistryЯзык: английский.Резюме или реферат: As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure..Примечания о наличии в документе библиографии/указателя: [References: 19 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | acylnitroso | catalysis | cycloaddition | ene reaction iodine | катализ | циклоприсоединение Ресурсы он-лайн:Щелкните здесь для доступа в онлайнНет реальных экземпляров для этой записи
Title screen
[References: 19 tit.]
As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure.
Для данного заглавия нет комментариев.
Личный кабинет оставить комментарий.