Reactions of diphenic acid with carbamide as a way to acyclic and cyclic amides of diphenic acid [Electronic resource] / V. А. Yanovskiy [et al.]
Уровень набора: (RuTPU)RU\TPU\book\169973, Bulletin of the Tomsk Polytechnic University / Tomsk Polytechnic University (TPU) = 2006-2007Язык: английский ; оригинала, русский.Страна: Россия.Описание: 1 файл (276 Кб)Серия: ChemistryРезюме или реферат: On the basis of reaction of diphenic acid with carbamide in the conditions of azeotropic water distillation a new way of producing acyclic and cyclic amides of diphenic acid has been found. The nature of aminating agent is shown to determine composition of reaction products: at aminating diphenic acid not substituted by carbamide the basic product is imide, whereas at aminating by substituted carbamide and amines it is corresponding monoamide. On the basis of experimental data the mechanism of the reactions is suggested..Примечания о наличии в документе библиографии/указателя: [Bibliography: p. 145 (11 titles)].Тематика: reactions | diphenic acid | acyclic amides | cyclic amides | azeotropic distillation | water | aminating agents | reaction products | aminating | imides | amines | monoamide | carbamides | experimental data | труды учёных ТПУ | электронный ресурс Ресурсы он-лайн:Щелкните здесь для доступа в онлайнНет реальных экземпляров для этой записи
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[Bibliography: p. 145 (11 titles)]
On the basis of reaction of diphenic acid with carbamide in the conditions of azeotropic water distillation a new way of producing acyclic and cyclic amides of diphenic acid has been found. The nature of aminating agent is shown to determine composition of reaction products: at aminating diphenic acid not substituted by carbamide the basic product is imide, whereas at aminating by substituted carbamide and amines it is corresponding monoamide. On the basis of experimental data the mechanism of the reactions is suggested.
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