Effect of high-temperature steam treatment on acidic and catalytic properties of catalysts for aromatization of lower alkanes / A. V. Vosmerikov, V. I. Erofeev

Уровень набора: Russian Journal of Applied Chemistry = 1928-Основной Автор-лицо: Vosmerikov, A. V.Альтернативный автор-лицо: Erofeev, V. I., specialist in the field of oil and gas business, Professor of Tomsk Polytechnic University, Doctor of technical sciences, 1946-, Vladimir IvanovichЯзык: английский.Страна: Россия.Резюме или реферат: The effect of high-temperature steam treatment of high-silica zeolites (HSZ) modified with zinc and gallium on their activity and catalyticproperties with respect to the aromatization of lower C3-C4 alkanes is studied. The introduction of modifying gallium and zinc additives into H-HSZ improves the activity and selectivity of the zeolite-containing catalysts with respect to the formation of aromatic hydrocarbons. The high-temperature steam treatment is shown to result in partial dealumination of the zeolite and decrease in the proton-donor power and concentration of acidic centers. The reactions applying to catalysts treated in this way yield products with a lower content of aromatic (especially polycyclic) hydrocarbons and a higher concentration of lower olefins..Аудитория: .Тематика: труды учёных ТПУ
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The effect of high-temperature steam treatment of high-silica zeolites (HSZ) modified with zinc and gallium on their activity and catalyticproperties with respect to the aromatization of lower C3-C4 alkanes is studied. The introduction of modifying gallium and zinc additives into H-HSZ improves the activity and selectivity of the zeolite-containing catalysts with respect to the formation of aromatic hydrocarbons. The high-temperature steam treatment is shown to result in partial dealumination of the zeolite and decrease in the proton-donor power and concentration of acidic centers. The reactions applying to catalysts treated in this way yield products with a lower content of aromatic (especially polycyclic) hydrocarbons and a higher concentration of lower olefins.

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