Efficient and economic halogenation of aryl amines via arenediazonium tosylate salts / Young Min Lee [et al.]

Уровень набора: Tetrahedron Letters, Scientific JournalАльтернативный автор-лицо: Young Min Lee;Mi Eun Moon;Filimonov, V. D., Russian chemist, Professor of the TPU, 1945-, Viktor Dmitrievich;Ki-Whan ChiЯзык: английский.Страна: .Резюме или реферат: Arenediazonium tosylate salts have been successfully employed as a new and efficient reagent in halogenation reactions. A novel and economic protocol has been developed for the bromination and chlorination of various anilines using arenediazonium tosylate salts. A wide variety of reaction conditions were studied in acetonitrile at either room temperature or 60 °C in the presence or absence of catalyst with good to excellent yields. A surprising result showed the formation of acetanilides as a major product of aniline and methyl-substituted aniline halogenations in high yields.Примечания о наличии в документе библиографии/указателя: [Referenses: p.7422 (29 tit.)].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[Referenses: p.7422 (29 tit.)]

Arenediazonium tosylate salts have been successfully employed as a new and efficient reagent in halogenation reactions. A novel and economic protocol has been developed for the bromination and chlorination of various anilines using arenediazonium tosylate salts. A wide variety of reaction conditions were studied in acetonitrile at either room temperature or 60 °C in the presence or absence of catalyst with good to excellent yields. A surprising result showed the formation of acetanilides as a major product of aniline and methyl-substituted aniline halogenations in high yields

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