Deposition of a Thin-Film CGO Electrolyte for Solid Oxide Fuel Cells / A. A. Soloviev [et al.]

Уровень набора: (RuTPU)RU\TPU\network\11477, Key Engineering Materials, Scientific JournalАльтернативный автор-лицо: Soloviev, A. A., specialist in the field of hydrogen energy, Associate Professor of Tomsk Polytechnic University, Candidate of technical sciences, 1977-, Andrey Aleksandrovich;Kovalchuk, A. N., specialist in the field of hydrogen energy, Technician of Tomsk Polytechnic University, 1988-, Anastasia Nikolaevna;Ionov, I. V., specialist in the field of hydrogen energy, Engineer of Tomsk Polytechnic University, 1988-, Igor Vyacheslavovich;Rabotkin, S. V.;Shipilova, A. V., specialist in the field of hydrogen energy, Researcher of Tomsk Polytechnic University, 1982-, Anna Viktorovna;Terentyev, D. N., specialist in the field of hydrogen energy, Techniques of Tomsk Polytechnic University, 1991-, Dmitry NikolaevichКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет (ТПУ), Физико-технический институт (ФТИ), Кафедра экспериментальной физики (ЭФ)Язык: английский.Серия: Chemical Engineering and TechnologyРезюме или реферат: Reducing the operating temperature of solid oxide fuel cells (SOFCs) from 800-1000°C is one of the main SOFC research goals. It can be achieved by lowering the thickness of an electrolyte (ZrO[2]:Y[2]O[3] (YSZ) is widely used as electrolyte material). On the other hand the problem can be solved by using of another electrolyte material with high ionic conductivity at intermediate temperatures. Therefore the present study deals with magnetron sputtering of ceria gadolinium oxide (CGO), which has a higher conductivity compared to YSZ. The microstructure of CGO layers deposited on porous NiO/YSZ substrates by reactive magnetron sputtering of Ce:Gd cathode is investigated. Current voltage characteristics (CVC) of a fuel cell with NiO/YSZ anode, CGO electrolyte and LSCF/CGO cathode were obtained. It was shown that the power density of a fuel cell with CGO electrolyte weakly depends on the operating temperature in the range of 650-750°C in contradistinction to YSZ electrolyte, and is about 600-650 mW/cm{2}..Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | электролиты | магнетронное распыление Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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Reducing the operating temperature of solid oxide fuel cells (SOFCs) from 800-1000°C is one of the main SOFC research goals. It can be achieved by lowering the thickness of an electrolyte (ZrO[2]:Y[2]O[3] (YSZ) is widely used as electrolyte material). On the other hand the problem can be solved by using of another electrolyte material with high ionic conductivity at intermediate temperatures. Therefore the present study deals with magnetron sputtering of ceria gadolinium oxide (CGO), which has a higher conductivity compared to YSZ. The microstructure of CGO layers deposited on porous NiO/YSZ substrates by reactive magnetron sputtering of Ce:Gd cathode is investigated. Current voltage characteristics (CVC) of a fuel cell with NiO/YSZ anode, CGO electrolyte and LSCF/CGO cathode were obtained. It was shown that the power density of a fuel cell with CGO electrolyte weakly depends on the operating temperature in the range of 650-750°C in contradistinction to YSZ electrolyte, and is about 600-650 mW/cm{2}.

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