Structural-and-phase states, crystallogeometric and crystallochemical parameters of membrane palladium-based alloys / V. D. Klopotov [et al.]

Альтернативный автор-лицо: Klopotov, V. D., physicist, Associate Professor of Tomsk Polytechnic University, Candidate of technical sciences, 1950-, Vladimir Dmitrievich;Potekaev, A. I., Alexandr;Kozyreva, R. A., Rima;Markova, T. N., Tatiana;Matunin, A. N., Alexandr;Klopotov, A. A., AnatolyКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет (ТПУ), Физико-технический институт (ФТИ), Кафедра высшей математики (ВМ)Язык: английский.Резюме или реферат: The results of the analysis of the ordered phase equilibria in binary Cu-Ni, Cu-Pd, and Ni-Pd, and ternary Cu-Ni-Pd systems are presented. It has been established that the packing index in disordered solid solutions of binary systems Cu-Ni, Cu-Pd, and Ni-Pd is close to the value of 0.74, and is accompanied by an insignificant deviation from the Zen law of concentration dependences of atomic volumes. A significant decrease in the packing index has been observed in the ordered phase with a B2 structure in the range of 40 at.% Pd in alloys of the binary system Cu-Pd. The correlation between the jump in hydrogen-permeability and the change in the effective size of atoms-components has been revealed. This phenomenon manifests itself in a significant decrease in the packing index in the ordered phase with a B2 structure in the range of 40 at.% Pd..Примечания о наличии в документе библиографии/указателя: [References: 24 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | фазовые диаграммы | геометрические параметры | проницаемость | упорядоченные фазы | палладий | сплавы | структурно-фазовые состояния Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: 24 tit.]

The results of the analysis of the ordered phase equilibria in binary Cu-Ni, Cu-Pd, and Ni-Pd, and ternary Cu-Ni-Pd systems are presented. It has been established that the packing index in disordered solid solutions of binary systems Cu-Ni, Cu-Pd, and Ni-Pd is close to the value of 0.74, and is accompanied by an insignificant deviation from the Zen law of concentration dependences of atomic volumes. A significant decrease in the packing index has been observed in the ordered phase with a B2 structure in the range of 40 at.% Pd in alloys of the binary system Cu-Pd. The correlation between the jump in hydrogen-permeability and the change in the effective size of atoms-components has been revealed. This phenomenon manifests itself in a significant decrease in the packing index in the ordered phase with a B2 structure in the range of 40 at.% Pd.

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