Broadening parameters of the H2O–He collisional system for astrophysical applications / T. M. Petrova [et al.]
Уровень набора: Journal of Molecular Spectroscopy, Scientific JournalЯзык: английский.Резюме или реферат: The water vapor line broadening γ and shift δ coefficients in the ν1 + ν2, ν2 + ν3, ν1 + ν3, 2ν3, 2ν1, 2ν2 + ν3, and ν1 + 2ν2 vibrational bands were obtained from the analysis of the H2O-He absorption spectra, recorded in the region from 5000 to 7500 cm−1 with the spectral resolution of 0.01 cm−1 using a Bruker IFS 125HR FTIR spectrometer. The vibrational bands 2ν3 and ν1 + 2ν2 were investigated for the first time. The calculations ofγ and δ were performed in the framework of the semi-classical method. The rotational contributions as well as the contributions connected with the accidental resonances were taken into account in the used H2O-He interaction potential. The analytical representation of the broadening coefficients γ at planetary temperatures was introduced and discussed..Примечания о наличии в документе библиографии/указателя: [References: p. 58 (30 tit.)].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | фурье-спектроскопия | квазиклассические методы | межмолекулярный потенциал Ресурсы он-лайн:Щелкните здесь для доступа в онлайнTitle screen
[References: p. 58 (30 tit.)]
The water vapor line broadening γ and shift δ coefficients in the ν1 + ν2, ν2 + ν3, ν1 + ν3, 2ν3, 2ν1, 2ν2 + ν3, and ν1 + 2ν2 vibrational bands were obtained from the analysis of the H2O-He absorption spectra, recorded in the region from 5000 to 7500 cm−1 with the spectral resolution of 0.01 cm−1 using a Bruker IFS 125HR FTIR spectrometer. The vibrational bands 2ν3 and ν1 + 2ν2 were investigated for the first time. The calculations ofγ and δ were performed in the framework of the semi-classical method. The rotational contributions as well as the contributions connected with the accidental resonances were taken into account in the used H2O-He interaction potential. The analytical representation of the broadening coefficients γ at planetary temperatures was introduced and discussed.
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