Modeling of Transalkylation Stage of Ethylbenzene Manufacturing with Zeolite-catalysts / S. A. Koshkin [et al.]

Уровень набора: Procedia EngineeringАльтернативный автор-лицо: Koshkin, S. A., Stanislav Aleksandrovich;Ignatova, L. S., Lyubov Sergeevna;Ivashkina, E. N., Chemical Engineer, Associate Professor of Tomsk Polytechnic University, Candidate of technical science, 1983-, Elena Nikolaevna;Dolganova, I. O., chemist, Junior research fellow Tomsk Polytechnic University, postgraduate student, candidate of technical Sciences, 1988-, Irena OlegovnaКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет (ТПУ), Институт природных ресурсов (ИПР), Кафедра химической технологии топлива и химической кибернетики (ХТТ)Язык: английский.Резюме или реферат: The analysis of industrial transalkylation reactor revealed regularities of catalyst activity and stability changes during its operation at change of basic technological parameters. A result of experimental data analysis, a list of possible reactions of transalkylation stage of ethylbenzene manufacturing zeolite-catalyst technology was developed. Values of Gibbs energies for change targets and adverse reactions, which were calculated with use of quantum chemistry methods, confirmed their thermodynamic probability at process conditions. The calculation results formed the basis of transalkylation process reaction network, needed to develop a mathematical model of ethylbenzene manufacturing zeolite-catalyst industrial technology..Примечания о наличии в документе библиографии/указателя: [References: p. 49-50 (17 tit.)].Тематика: электронный ресурс | труды учёных ТПУ | transalkylation | mathematical models | zeolite-catalyst | трансалкилирование | математические модели | цеолитные катализаторы Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: p. 49-50 (17 tit.)]

The analysis of industrial transalkylation reactor revealed regularities of catalyst activity and stability changes during its operation at change of basic technological parameters. A result of experimental data analysis, a list of possible reactions of transalkylation stage of ethylbenzene manufacturing zeolite-catalyst technology was developed. Values of Gibbs energies for change targets and adverse reactions, which were calculated with use of quantum chemistry methods, confirmed their thermodynamic probability at process conditions. The calculation results formed the basis of transalkylation process reaction network, needed to develop a mathematical model of ethylbenzene manufacturing zeolite-catalyst industrial technology.

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