Coal char oxidation kinetics in air medium / A. G. Korotkikh, K. V. Slusarskiy (Slyusarsky), I. V. Sorokin

Уровень набора: (RuTPU)RU\TPU\network\4526, MATEC Web of ConferencesОсновной Автор-лицо: Korotkikh, A. G., specialist in the field of power engineering, Associate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences, 1976-, Aleksandr GennadievichАльтернативный автор-лицо: Slusarskiy (Slyusarsky), K. V., specialist in the field of power engineering, assistant of Tomsk Polytechnic University, 1990-, Konstantin Vitalievich;Sorokin, I. V., IvanКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет (ТПУ), Энергетический институт (ЭНИН), Кафедра атомных и тепловых электростанций (АТЭС)Язык: английский.Резюме или реферат: Study of oxidation kinetics for three types of coal char with different carbon content in air is presented. The coal char powders of anthracite, bituminous T-grade coal and 2B-grade lignite with particle size less than 80 [mu]m were tested. The coal char oxidation was researched by isothermal method via simultaneous TG-DSC analyzer Netzsch STA 449 Jupiter F3 in the temperature range of 1000-1200 °C. Measurements were carried out at ambient pressure. Volumetric flow rate of oxidizing medium into analyser chamber was 250 ml/min. Flow consisted of air and argon with volumetric ratio 24/1. Carbon average rate of oxidation reaction at each temperature were defined based on experimental results. Kinetic constants (the frequency factor and activation energy) were defined for Arrhenius equation modified with three submodels: volumetric model, shrinking core model and random pore model. The activation energy values for anthracite are 1,6-1,7 times higher than for chars of bituminous coal and lignite..Примечания о наличии в документе библиографии/указателя: [References: 7 tit.].Тематика: электронный ресурс | труды учёных ТПУ | кинетика окисления | угли | воздушные среды | полукоксы | анализаторы | тепловые электростанции | твердые топлива | утилизация | дымовые газы | газификация Ресурсы он-лайн:Щелкните здесь для доступа в онлайн | Щелкните здесь для доступа в онлайн
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[References: 7 tit.]

Study of oxidation kinetics for three types of coal char with different carbon content in air is presented. The coal char powders of anthracite, bituminous T-grade coal and 2B-grade lignite with particle size less than 80 [mu]m were tested. The coal char oxidation was researched by isothermal method via simultaneous TG-DSC analyzer Netzsch STA 449 Jupiter F3 in the temperature range of 1000-1200 °C. Measurements were carried out at ambient pressure. Volumetric flow rate of oxidizing medium into analyser chamber was 250 ml/min. Flow consisted of air and argon with volumetric ratio 24/1. Carbon average rate of oxidation reaction at each temperature were defined based on experimental results. Kinetic constants (the frequency factor and activation energy) were defined for Arrhenius equation modified with three submodels: volumetric model, shrinking core model and random pore model. The activation energy values for anthracite are 1,6-1,7 times higher than for chars of bituminous coal and lignite.

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