Zn@ZIF-67 as Catalysts for the Knoevenagel Condensation of Aldehyde Derivatives with Malononitrile / A. Zanon, S. Chaemchuen, F. V. K. Verpoort
Уровень набора: Catalysis LettersЯзык: английский.Страна: .Резюме или реферат: Three different bimetallic zinc-cobalt zeolitic imidazolate frameworks (ZIFs) were successfully synthesized at room temperature in water through a green and simple procedure and tested as catalysts for the Knoevenagel condensation reaction between p-Br-benzaldehyde and malononitrile as model reaction. The materials were characterized with various techniques (XRD, ICP-AES, SEM, N2 adsorption–desorption, TGA) and displayed excellent activities and selectivities. Moreover, the crystalline structure was preserved and the catalysts could be reused at least four times with negligible loss of activity..Примечания о наличии в документе библиографии/указателя: [References: 43 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | гетерогенный катализ | металлоорганические комплексы | конденсация | каркасы Ресурсы он-лайн:Щелкните здесь для доступа в онлайнНет реальных экземпляров для этой записи
Title screen
[References: 43 tit.]
Three different bimetallic zinc-cobalt zeolitic imidazolate frameworks (ZIFs) were successfully synthesized at room temperature in water through a green and simple procedure and tested as catalysts for the Knoevenagel condensation reaction between p-Br-benzaldehyde and malononitrile as model reaction. The materials were characterized with various techniques (XRD, ICP-AES, SEM, N2 adsorption–desorption, TGA) and displayed excellent activities and selectivities. Moreover, the crystalline structure was preserved and the catalysts could be reused at least four times with negligible loss of activity.
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