Investigation of the ro-vibrational energy structure of (0101, F1) and (0101, F2) states of the 28SiH4 molecule / N. I. Raspopova
Уровень набора: Atmospheric and Oceanic Optics, Scientific JournalЯзык: английский.Страна: .Резюме или реферат: An analysis of the high-resolution vibrational-rotational IR spectrum of ν2 + ν4 (F1) and ν2 + ν4(F2) bending absorption bands of the 28SiH4 molecule is carried out for the first time using the SPHETOM software. Approximately 618 experimental transitions with Jmax = 8 are assigned to ν2 + ν4 (F1) and ν2 + ν4 (F2) bands. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for these vibrational bands are derived from the weighted fit of experimental line positions. The set of parameters obtained reproduces the initial experimental data with an accuracy close to the experimental uncertainties drms = 8 × 10-4 cm-1..Примечания о наличии в документе библиографии/указателя: [References: 29 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | bending vibrations | overtones | tetrahedral splittings | resonance interactions | изгибные колебания | обертоны | тетраэдрические расщепления | резонансные взаимодействия Ресурсы он-лайн:Щелкните здесь для доступа в онлайнTitle screen
[References: 29 tit.]
An analysis of the high-resolution vibrational-rotational IR spectrum of ν2 + ν4 (F1) and ν2 + ν4(F2) bending absorption bands of the 28SiH4 molecule is carried out for the first time using the SPHETOM software. Approximately 618 experimental transitions with Jmax = 8 are assigned to ν2 + ν4 (F1) and ν2 + ν4 (F2) bands. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for these vibrational bands are derived from the weighted fit of experimental line positions. The set of parameters obtained reproduces the initial experimental data with an accuracy close to the experimental uncertainties drms = 8 × 10-4 cm-1.
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