Parameters of Aluminum Nanopowders Activity after Long-Term Storage in an Airtight Container / A. P. Ilyin, D. V. Tikhonov, A. V. Mostovshchikov

Уровень набора: Propellants, Explosives, PyrotechnicsОсновной Автор-лицо: Ilyin, A. P., chemist, Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, 1949-, Aleksandr PetrovichАльтернативный автор-лицо: Tikhonov, D. V., Specialist in the field of electric power engineering, Senior researcher of Tomsk Polytechnic University, Candidate of technical sciences, 1965-, Dmitry Vladimirovich;Mostovshchikov, A. V., Chemist, Engineer of Tomsk Polytechnic University, 1989-, Andrey VladimirovichКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет, Школа базовой инженерной подготовки, Отделение естественных наук;Национальный исследовательский Томский политехнический университет, Инженерная школа энергетики, Отделение электроэнергетики и электротехники (ОЭЭ)Язык: английский.Страна: .Резюме или реферат: The work has established the change in the activity parameters of aluminum nanopowders produced by electric explosion of a wire during their storage in an airtight container. The change in the characteristics of the nanopowders using four activity parameters was measured by benchmarking their activity after the production, passivation and keeping for 10–20 days and after their storage for 16 years. It was also established that after long-term storage, the temperature of oxidation initiation for the nanopowders in air has increased; the increment of mass during oxidation at up to 800?°C for all specimens has increased, while the content of metallic aluminum has decreased. The electrical double layer on the surface of aluminum nanoparticles during storing even in an airtight container changes with time and does not provide the protective function. In this connection, the future application of aluminum nanopowders in high-energy materials is not feasible without solving the problem of their stability. According to the results, electric-explosion aluminum nanopowder is an unstable aluminum-air system even in an airtight container..Примечания о наличии в документе библиографии/указателя: [References: p. 752-753 (25 tit.)].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | алюминий | проволока | электрический взрыв | нанопорошки | химическая активность Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: p. 752-753 (25 tit.)]

The work has established the change in the activity parameters of aluminum nanopowders produced by electric explosion of a wire during their storage in an airtight container. The change in the characteristics of the nanopowders using four activity parameters was measured by benchmarking their activity after the production, passivation and keeping for 10–20 days and after their storage for 16 years. It was also established that after long-term storage, the temperature of oxidation initiation for the nanopowders in air has increased; the increment of mass during oxidation at up to 800?°C for all specimens has increased, while the content of metallic aluminum has decreased. The electrical double layer on the surface of aluminum nanoparticles during storing even in an airtight container changes with time and does not provide the protective function. In this connection, the future application of aluminum nanopowders in high-energy materials is not feasible without solving the problem of their stability. According to the results, electric-explosion aluminum nanopowder is an unstable aluminum-air system even in an airtight container.

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