Determining the Parameters of the Effective Rovibrational Hamiltonian of the ν7+ν8 Band of the Ethylene-1-13C Molecule / Yu. S. Aslapovskaya
Уровень набора: Russian Physics JournalЯзык: английский.Резюме или реферат: The spectrum of the ν7 + ν8 band of the ethylene-1-13C (13C12СH4) molecule is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range from 1500 to 2100 cm-1 with a resolution of 0.0025 cm-1. As a result of analysis of the experimental spectrum, more than 1000 transitions belonging to the ν7 + ν8 band are assigned. Parameters of the Hamiltonian obtained as a result of solving the inverse spectroscopic problem reproduce 400 initial experimental energies with error close to the experimental one..Примечания о наличии в документе библиографии/указателя: [References: 25 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | молекулярная спектроскопия | гамильтонианы | вращательные состояния | этилен Ресурсы он-лайн:Щелкните здесь для доступа в онлайнНет реальных экземпляров для этой записи
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[References: 25 tit.]
The spectrum of the ν7 + ν8 band of the ethylene-1-13C (13C12СH4) molecule is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range from 1500 to 2100 cm-1 with a resolution of 0.0025 cm-1. As a result of analysis of the experimental spectrum, more than 1000 transitions belonging to the ν7 + ν8 band are assigned. Parameters of the Hamiltonian obtained as a result of solving the inverse spectroscopic problem reproduce 400 initial experimental energies with error close to the experimental one.
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