Structure and electrochemical characterization of SnOx/Sn@MWCNT composites formed by pulsed ion beam irradiation / P. М. Korusenko [et al.]

Уровень набора: Journal of Alloys and CompoundsАльтернативный автор-лицо: Korusenko, P. М., Petr Mikhaylovich;Nesov, S. N., Sergey Nikolaevich;Bolotov, V. V., Valery Viktorovich;Povoroznyuk, S. N., Sergey Nikolaevich;Stenkin, Yu. A., Yury Alexeevich;Pushkarev, A. I., physicist, Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, Senior researcher, 1954-, Aleksandr Ivanovich;Fedorovskaya, E. O., Ekaterina Olegovna;Smirnov, D. A., Dmitry AleksandrovichКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет, Инженерная школа новых производственных технологий, Отделение материаловеденияЯзык: английский.Резюме или реферат: The influence of irradiation by pulsed ion beam on the morphology, structure, and chemical composition of a composite based on multiwalled carbon nanotubes (MWCNTs) and tin dioxide (SnO2-x@MWCNTs) was investigated. It has been established that irradiation of the composite by pulsed ion beam leads to the formation of Sn/SnOx core-shell nanoparticles, which adhere to the surface of the MWCNTs. The “core” is metallic Sn and the “shell” is amorphous SnOx. A uniform distribution of Sn/SnOx nanoparticles on the surface of the MWCNTs was noted, and the maximal concentration of tin in both volume and surface layer was achieved by triple irradiation with an energy density of 0.5?J/cm2. This composite exhibited good electrochemical performance as an anode material for lithium-ion batteries, delivering 1494?mA?h?g-1 as a first discharge capacity and 634?mA?h?g-1 discharge capacity (72% capacity retention) after 30 cycles of charge/discharge..Примечания о наличии в документе библиографии/указателя: [References: 44 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | pulsed ion beam | tin-tin oxide | core-shell | multiwalled carbon nanotubes | composite | Li-ion batteries | ионные пучки | оксид олова | оболочки | нанотрубки Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: 44 tit.]

The influence of irradiation by pulsed ion beam on the morphology, structure, and chemical composition of a composite based on multiwalled carbon nanotubes (MWCNTs) and tin dioxide (SnO2-x@MWCNTs) was investigated. It has been established that irradiation of the composite by pulsed ion beam leads to the formation of Sn/SnOx core-shell nanoparticles, which adhere to the surface of the MWCNTs. The “core” is metallic Sn and the “shell” is amorphous SnOx. A uniform distribution of Sn/SnOx nanoparticles on the surface of the MWCNTs was noted, and the maximal concentration of tin in both volume and surface layer was achieved by triple irradiation with an energy density of 0.5?J/cm2. This composite exhibited good electrochemical performance as an anode material for lithium-ion batteries, delivering 1494?mA?h?g-1 as a first discharge capacity and 634?mA?h?g-1 discharge capacity (72% capacity retention) after 30 cycles of charge/discharge.

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