Study of the laws of oxidation of biodiesel / S. A. Yudaev, E. N. Ivashkina, V. N. Sapunov, M. C. Voronov
Уровень набора: (RuTPU)RU\TPU\network\2008, IOP Conference Series: Materials Science and EngineeringЯзык: английский.Резюме или реферат: The paper discusses in detail the first stage of the catalytic oxidation of fatty acid methyl esters with atmospheric oxygen. According to the data obtained as a result of processing the kinetic data, it was concluded that the reactivity of the components of biodiesel. It is established that polyunsaturated and monounsaturated compounds have different reactivity from each other. The kinetic pattern of consumption of unsaturated components of biodiesel was set up and kinetic constants were calculated, which are equal to: oxidation of C18/1 k1 = 0.106±0.008 h-1, and oxidation of C18/2 k2 = 0.269±0.005 h-1, respectively..Примечания о наличии в документе библиографии/указателя: [References: 10 tit.].Тематика: электронный ресурс | труды учёных ТПУ | окисление | биодизели Ресурсы он-лайн:Щелкните здесь для доступа в онлайн | Щелкните здесь для доступа в онлайнНет реальных экземпляров для этой записи
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[References: 10 tit.]
The paper discusses in detail the first stage of the catalytic oxidation of fatty acid methyl esters with atmospheric oxygen. According to the data obtained as a result of processing the kinetic data, it was concluded that the reactivity of the components of biodiesel. It is established that polyunsaturated and monounsaturated compounds have different reactivity from each other. The kinetic pattern of consumption of unsaturated components of biodiesel was set up and kinetic constants were calculated, which are equal to: oxidation of C18/1 k1 = 0.106±0.008 h-1, and oxidation of C18/2 k2 = 0.269±0.005 h-1, respectively.
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