Extended analysis of the v12 band of 12C2H4 for astrophysical applications: Line strengths, widths, and shifts / O. N. Ulenekov, E. S. Bekhtereva, O. V. Gromova [et al.]

Уровень набора: Journal of Quantitative Spectroscopy and Radiative TransferАльтернативный автор-лицо: Ulenekov, O. N., physicist, Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, 1949-, Oleg Nikolaevich;Bekhtereva, E. S., physicist, Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, 1974-, Elena Sergeevna;Gromova, O. V., physicist, Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences, 1982-, Olga Vasilievna;Kakaulin, A. N., physicist, Technician of Tomsk Polytechnic University, 1998-, Aleksey Nikolaevich;Sydow, Ch., Christian;Bauerecker, S., SigurdКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет, Исследовательская школа физики высокоэнергетических процессов, (2017- )Язык: английский.Страна: .Резюме или реферат: The high-resolution infrared spectra of 12C2H4 were analyzed in the region of 1360 - 1530 cm-1, where the strong V12 band is located. 998 line strengths (1491 transitions) were determined from the fit of their line shapes with a Hartmann-Tran profile (Jmax=48 and Kamax=17) which is about two times more than in the preceding studies. These data were used in the fit of the effective dipole moment parameters and six such parameters were obtained which reproduce the strengths of the 998 initial lines (1491 transitions) with the drms=2.31%. Self-broadening and self-shift coefficients were determined from the multi-spectrum analysis for sets of lines (JKa=KaKc)<-(JKaKc), Ka=0,1,2,3,4,5 (in general, 253 lines for determination of self-broadening coefficients and 225 lines for determination of self-shift coefficients). The line list of 19186 transitions is documented..Примечания о наличии в документе библиографии/указателя: [References: 81 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | high-resolution spectra | ethylene | спектры высокого разрешения Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: 81 tit.]

The high-resolution infrared spectra of 12C2H4 were analyzed in the region of 1360 - 1530 cm-1, where the strong V12 band is located. 998 line strengths (1491 transitions) were determined from the fit of their line shapes with a Hartmann-Tran profile (Jmax=48 and Kamax=17) which is about two times more than in the preceding studies. These data were used in the fit of the effective dipole moment parameters and six such parameters were obtained which reproduce the strengths of the 998 initial lines (1491 transitions) with the drms=2.31%. Self-broadening and self-shift coefficients were determined from the multi-spectrum analysis for sets of lines (JKa=KaKc)<-(JKaKc), Ka=0,1,2,3,4,5 (in general, 253 lines for determination of self-broadening coefficients and 225 lines for determination of self-shift coefficients). The line list of 19186 transitions is documented.

Российский фонд фундаментальных исследований 18–02–00819 A

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