The low-temperature specific heat of MWCNTs / V. V. Sumarokov, A. Jeowski, D. Szewczyk [et al.]

Уровень набора: Low Temperature PhysicsАльтернативный автор-лицо: Sumarokov, V. V., Vladimir Victorovich;Jeowski, A.;Szewczyk, D., Daria;Bagatskii, M. I., Michail Ivanovich;Ponomarev, A. N., Aleksandr Nikolaevich;Kuznetsov, V. V., Vadim Vladimirovich;Moseenkov, S. I., Sergey Ivanovich;Barabashko, M. S., Physicist, Researcher of Tomsk Polytechnic University, Doctor of physical and mathematical sciences, 1987-, Maksim SergeevichКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет, Исследовательская школа физики высокоэнергетических процессов, (2017- )Язык: английский.Страна: .Резюме или реферат: The specific heat of multi-walled carbon nanotubes (MWCNTs) with a low defectiveness and with a low content of inorganic impurities has been measured in the temperature range from 1.8 to 275 K by the thermal relaxation method. The elemental composition and morphology of the MWCNTs were determined using scanning electron microscopy analysis and energy dispersion x-ray spectroscopy. The MWCNTs were prepared by chemical catalytic vapor deposition and have mean diameters from 7 nm up to 18 nm and lengths in some tens of microns. MWCNTs purity is over 99.4 at.%. The mass of the samples ranged from 2-4 mg. It was found that the temperature dependence of the specific heat of the MWCNTs differs significantly from other carbon materials (graphene, bundles of SWCNTs, graphite, diamond) at low temperatures. The specific heat of MWCNTs systematically decreases with increasing diameter of the tubes at low temperatures. The character of the temperature dependence of the specific heat of the MWCNTs with different diameters demonstrates the manifestation of different dimensions from 1D to 3D, depending on the temperature regions. The crossover temperatures are about 6 and 40 K. In the vicinity of these temperatures, a hysteresis is observed..Примечания о наличии в документе библиографии/указателя: [References: 55 tit.].Тематика: электронный ресурс | труды учёных ТПУ | низкотемпературная теплоемкость | углеродные нанотрубки | низкие температуры | гистерезис | дефектность | примеси Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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[References: 55 tit.]

The specific heat of multi-walled carbon nanotubes (MWCNTs) with a low defectiveness and with a low content of inorganic impurities has been measured in the temperature range from 1.8 to 275 K by the thermal relaxation method. The elemental composition and morphology of the MWCNTs were determined using scanning electron microscopy analysis and energy dispersion x-ray spectroscopy. The MWCNTs were prepared by chemical catalytic vapor deposition and have mean diameters from 7 nm up to 18 nm and lengths in some tens of microns. MWCNTs purity is over 99.4 at.%. The mass of the samples ranged from 2-4 mg. It was found that the temperature dependence of the specific heat of the MWCNTs differs significantly from other carbon materials (graphene, bundles of SWCNTs, graphite, diamond) at low temperatures. The specific heat of MWCNTs systematically decreases with increasing diameter of the tubes at low temperatures. The character of the temperature dependence of the specific heat of the MWCNTs with different diameters demonstrates the manifestation of different dimensions from 1D to 3D, depending on the temperature regions. The crossover temperatures are about 6 and 40 K. In the vicinity of these temperatures, a hysteresis is observed.

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