The promoting effect of pyridine ligands in the Pd-catalysed Heck–Matsuda reaction / W. Khodja [et al.]

Уровень набора: New Journal of ChemistryАльтернативный автор-лицо: Khodja, W., Walid;Leclair, A., Alexandre;Rull-Barrull, J., Jordi;Zammattio, F., Francoise;Kutonova, K. V., chemist, Engineer of Tomsk Polytechnic University, 1990-, Ksenia Valentinovna;Trusova, M. E., organic chemist, Associate professor of Tomsk Polytechnic University, Candidate of chemical sciences, 1982-, Marina Evgenievna;Felpin, F.-Х., Francois-Xavier;Rodriguez, Z. M., Zubiri MireiaКоллективный автор (вторичный): Национальный исследовательский Томский политехнический университет (ТПУ), Институт физики высоких технологий (ИФВТ), Кафедра биотехнологии и органической химии (БИОХ)Язык: английский.Резюме или реферат: An efficient Pd-catalyzed arylation reaction of challenging acyclic olefins, in the presence of an organic ligand, has been disclosed. Commercially available cheap pyridine-based ligands are able to promote good to excellent yields for poorly efficient Heck–Matsuda arylation reactions of several allylic alcohols. A wide range of electronically different arenediazonium salts bearing either electron-releasing or withdrawing groups have been used allowing the synthesis of a range of Я-aryl-methoxy-lactols. The catalytic system has been optimised, along with the reaction conditions, in order to achieve remarkable yields in less than 1 h..Примечания о наличии в документе библиографии/указателя: [References: 48 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ Ресурсы он-лайн:Щелкните здесь для доступа в онлайн
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Title screen

[References: 48 tit.]

An efficient Pd-catalyzed arylation reaction of challenging acyclic olefins, in the presence of an organic ligand, has been disclosed. Commercially available cheap pyridine-based ligands are able to promote good to excellent yields for poorly efficient Heck–Matsuda arylation reactions of several allylic alcohols. A wide range of electronically different arenediazonium salts bearing either electron-releasing or withdrawing groups have been used allowing the synthesis of a range of Я-aryl-methoxy-lactols. The catalytic system has been optimised, along with the reaction conditions, in order to achieve remarkable yields in less than 1 h.

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