Analysis of the High-Resolution Spectrum of Molecules in Doublet Electronic States: Fundamental ν3 Band of Chlorine Dioxide (16O35Cl16O) in the Ground Electronic State X 2B1 / M. A. Merkulova, A. N. Kakaulin, O. V. Gromova, E. S. Bekhtereva
Уровень набора: Optics and SpectroscopyЯзык: английский.Резюме или реферат: Using a Bruker IFS 125 HR Fourier spectrometer, the vibrational-rotational structure of the ClO2 molecule band ν3ν3 has been recorded with a resolution of 0.0015 cm-1. This band has been analyzed using an improved model of the effective Hamiltonian and a new computer program developed to analyze vibrational-rotational spectra of free radical molecules with an open shell, taking into account spin-rotational interactions. About 4200 transitions belonging to this band have been assigned with maximum values NmaxNmax = 68 and KmaxaKamax = 21. Subsequently, we have used these to determine a set of 13 spectroscopic parameters of the investigated vibrational state. The standard deviation results in the value drmsdrms = 2.4 × 10-4 cm-1..Примечания о наличии в документе библиографии/указателя: [References: 31 tit.].Аудитория: .Тематика: электронный ресурс | труды учёных ТПУ | molecular spectroscopy | chlorine dioxide | vibrational-rotational Hamiltonian for doublet electronic state | молекулярная спектроскопия | диоксид хлора Ресурсы он-лайн:Щелкните здесь для доступа в онлайнTitle screen
[References: 31 tit.]
Using a Bruker IFS 125 HR Fourier spectrometer, the vibrational-rotational structure of the ClO2 molecule band ν3ν3 has been recorded with a resolution of 0.0015 cm-1. This band has been analyzed using an improved model of the effective Hamiltonian and a new computer program developed to analyze vibrational-rotational spectra of free radical molecules with an open shell, taking into account spin-rotational interactions. About 4200 transitions belonging to this band have been assigned with maximum values NmaxNmax = 68 and KmaxaKamax = 21. Subsequently, we have used these to determine a set of 13 spectroscopic parameters of the investigated vibrational state. The standard deviation results in the value drmsdrms = 2.4 × 10-4 cm-1.
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