| 000 | 03319naa2a2200433 4500 | ||
|---|---|---|---|
| 001 | 565831 | ||
| 005 | 20231030031528.0 | ||
| 035 | _a(RuTPU)RU\TPU\prd\262201 | ||
| 035 | _aRU\TPU\prd\262200 | ||
| 090 | _a565831 | ||
| 100 | _a20160908a2016 k y0rusy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aRU | ||
| 135 | _adrcn ---uucaa | ||
| 200 | 1 |
_aOxidative fluorination of iridium metal for urban mining: Kinetic studies _bElectronic resource _fB. V. Sakhnevich [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 93 (15 tit.)] | ||
| 330 | _aThe process of oxidative fluorination of a compact iridium metal has been studied. For this purpose, tetrafluoridobromates(III) of alkali and alkaline-earth metals were chosen as oxidizing agents with numerous advantages. The main results of this work include the kinetic dependencies for the two following processes: 1) interaction of iridium with molten potassium tetrafluoridobromate; and 2) interaction of iridium with a solution of potassium tetrafluoridobromate in liquid bromine trifluoride. In both cases it has been found out that iridium can be transformed into its soluble fluorinated derivative; the reaction with molten potassium tetrafluoridobromate proceeds almost 50 times faster (in comparison to the interaction in BrF3 solution) and can be potentially applied for the practical purposes. | ||
| 461 | 1 |
_0(RuTPU)RU\TPU\prd\247369 _x2405-6537 _tResource-Efficient Technologies _oelectronic scientific journal _fNational Research Tomsk Polytechnic University (TPU) _d2015- |
|
| 463 | 1 |
_0(RuTPU)RU\TPU\prd\262183 _tVol. 2, Iss. 2 _v[P. 89-93] _d2016 |
|
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aиридий | |
| 610 | 1 | _aфторирование | |
| 610 | 1 | _aкинетика | |
| 610 | 1 | _aщелочно-земельные металлы | |
| 610 | 1 | _aокислители | |
| 701 | 1 |
_aSakhnevich _bB. V. _gBogdan |
|
| 701 | 1 |
_aMalin _bA. V. _gArtem |
|
| 701 | 1 |
_aShagalov _bV. V. _cchemist _cassociate professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1982- _gVladimir Vladimirovich _2stltpush _3(RuTPU)RU\TPU\pers\31530 |
|
| 701 | 1 |
_aSobolev _bV. I. _cChemical Engineer _cEngineer-designer of Tomsk Polytechnic University _f1989- _gVasily Igorevich _2stltpush _3(RuTPU)RU\TPU\pers\31294 |
|
| 701 | 1 |
_aOstvald _bR. V. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1980- _gRoman Vyacheslavovich _2stltpush _3(RuTPU)RU\TPU\pers\31221 |
|
| 701 | 1 |
_aIvlev _bS. I. _cChemical Engineer _cassistant Tomsk Polytechnic University, candidate of chemical Sciences _f1987- _gSergey Ivanovich _2stltpush _3(RuTPU)RU\TPU\pers\31276 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bФизико-технический институт (ФТИ) _bКафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ) _h56 _2stltpush _3(RuTPU)RU\TPU\col\18733 |
| 801 | 1 |
_aRU _b63413507 _c20090623 _gPSBO |
|
| 801 | 2 |
_aRU _b63413507 _c20180830 _gPSBO |
|
| 856 | 4 | _uhttp://earchive.tpu.ru/handle/11683/50209 | |
| 942 | _cBK | ||