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100 _a20101103a1998 k y0engy50 ba
101 0 _aeng
102 _aUS
200 1 _a(E,E)-1,4-Distyrylbenzene and Its Bisepoxy, Bis(dihydroxy), and Bis(dichloromethylene) Derivatives
_fM. S. Yusubov, V. D. Filimonov, V. D. Ogorodnikov
330 _aConvenient preparative methods for indirect epoxidation and dichlorocyclopropanation of the two exocyclic double bonds in (E,E)-1,4-distyrylbenzene have been proposed. The procedure for epoxidation includes conjugate electrophilic bromination of (E,E)-1,4-distyrylbenzene with N-bromosuccinimide in formic acid, followed by treatment of the addition products with alkali under conditions of phase-transfer catalysis. The procedure also applies to styrene and stilbene derivatives. Dichlorocyclopropanation of (E,E)-1,4-distyrylbenzene smoothly occurs on heating in chloroform in the presence of alkali with no phase-transfer catalyst.
333 _aВ фонде НТБ ТПУ отсутствует
461 _tRussian Journal of Organic Chemistry
_d1965-
463 _tVol. 34, iss. 1
_vP. 81-85
_d1998
610 1 _aтруды учёных ТПУ
700 1 _aYusubov
_bM. S.
_cchemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1961-
_gMekhman Suleiman-Ogly (Suleimanovich)
_xTPU
_2stltpush
_3(RuTPU)RU\TPU\pers\31833
701 1 _aFilimonov
_bV. D.
_cRussian chemist
_cProfessor of the TPU
_f1945-
_gViktor Dmitrievich
_xTPU
_2stltpush
_3(RuTPU)RU\TPU\pers\26423
701 1 _aOgorodnikov
_bV. D.
_4070
801 1 _aRU
_b63413507
_c20101103
801 2 _aRU
_b63413507
_c20160418
_gRCR
942 _cBK