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035			_a(RuTPU)RU\TPU\tpu\22763
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090			_a598955
100			_a20130226a2011 k y0engy50 ba
101	0		_aeng
102			_aUS
200	1		_aGold nanoparticles supported on magnesium oxide for CO oxidation _fS. A. C. Carabineiro [et al.]
300			_aProceedings 11th International Conference (TNT2010) Trends in NanoTechnology
320			_aReferences: 46 tit.
330			_aAu was loaded (1 wt%) on a commercial MgO support by three different methods: double impregnation, liquid-phase reductive deposition and ultrasonication. Samples were characterised by adsorption of N2 at -96°C, temperature-programmed reduction, high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction. Upon loading with Au, MgO changed into Mg(OH)2 (the hydroxide was most likely formed by reaction with water, in which the gold precursor was dissolved). The size range for gold nanoparticles was 2-12 nm for the DIM method and 3-15 nm for LPRD and US. The average size of gold particles was 5.4 nm for DIM and larger than 6.5 for the other methods. CO oxidation was used as a test reaction to compare the catalytic activity. The best results were obtained with the DIM method, followed by LPRD and US. This can be explained in terms of the nanoparticle size, well known to determine the catalytic activity of gold catalysts.
333			_aВ фонде НТБ ТПУ отсутствует
461			_tNanoscale Research Letters _d2006-
463			_tVol. 6, Art. 435 _v6 p. _d2011
610	1		_aтруды учёных ТПУ
701		1	_aCarabineiro _bS. A. C.
701		1	_aBogdanchikova _bN.
701		1	_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 _4070
701		1	_aTavares _bP. B.
701		1	_aFernandes _bL. S. G.
701		1	_aFigueiredo _bJ. L.
801		1	_aRU _b63413507 _c20130226
801		2	_aRU _b63413507 _c20130226 _gRCR
942			_cBK