| 000 | 02004nam1a2200313 4500 | ||
|---|---|---|---|
| 001 | 599031 | ||
| 005 | 20231030033814.0 | ||
| 035 | _a(RuTPU)RU\TPU\tpu\22860 | ||
| 035 | _aRU\TPU\tpu\22859 | ||
| 090 | _a599031 | ||
| 100 | _a20130319a2005 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aDE | ||
| 200 | 1 |
_aInfluence of modifying additives on formation of supported copper nanoparticles _fA. N. Pestryakov [et al.] |
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| 300 | _aThis special issue of The European Physical Journal D contains papers which have been presented at the 12th InternationalSymposium on Small Particles and Inorganic Clusters. ISSPIC-12 was held from September 6th to 10th, 2004, in Nanjing, China. | ||
| 320 | _aReferences: p. 58 (22 tit.) | ||
| 330 | _aThe influence of modifying additives of Ce, Zr, La and Cs oxides on changes of electronic state of supported copper during the catalytic reaction of butane complete oxidation has been studied by the methods of IR-spectroscopy of adsorbed CO, XPS, EXAFS and XRD. The modifying additions of cerium and zirconium oxides stabilize the ionic state of copper, while lanthanum and cesium oxides decrease the effective charge of copper ions. The observed effects are caused by variation in metal dispersivity in the modified samples and by electron donor-acceptor interaction of the surface atoms and ions of copper with the modifier. | ||
| 333 | _aВ фонде НТБ ТПУ отсутствует | ||
| 461 |
_tThe European physical journal D : Atomic, molecular and optical physics _d1998- |
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| 463 |
_tVol. 34, iss. 1-3 _vP. 55-58 _d2005 |
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| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 _4070 |
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| 701 | 1 |
_aLunin _bV. V. |
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| 701 | 1 |
_aKochubey _bD. I. |
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| 701 | 1 |
_aStakheev _bA. Yu. |
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| 701 | 1 |
_aSmolentseva _bE. |
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| 801 | 1 |
_aRU _b63413507 _c20130226 |
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| 801 | 2 |
_aRU _b63413507 _c20130319 _gRCR |
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| 942 | _cBK | ||