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035 _a(RuTPU)RU\TPU\tpu\22943
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100 _a20130326d2003 k y0engy50 ba
101 0 _aeng
102 _aRU
200 1 _aProcessing of liquid radioactive wastes containing organophosphorus compounds
_fV. I. Karpenko, O. A. Ozhereliev, A. N. Pestryakov
320 _aReferences: p. 317 (5 tit.)
330 _aNeutralization of liquid radioactive P-containing wastes of nuclear power using CaO powder as absorbent and catalyst has been studied in uniflow system. During the process all organophosphorus compounds were absorbed and converted to corrosion-inactive calcium phosphates. Radioactive elements were remained in the solid phase. Diluent hydrocarbons and organic fragments of P-containing molecules were oxidized by air to CO2+H2O. In the case of applying the additional catalytic reactor containing honecomb supported Pt catalyst the degree of neutralization of gas emissions reached 95-98 %. On the base of thermodynamic calculations and laboratory tests a technological scheme of neutralization of the radioactive liquid P-containing wastes was suggested.
333 _aВ фонде НТБ ТПУ отсутствует
463 _tXVI International Conference on Chemical Reactors CHEMREACTOR-16, Berlin, Germany, December 1-5, 2003
_oabstracts
_vP. 314-317
_d2003
610 1 _aтруды учёных ТПУ
700 1 _aKarpenko
_bV. I.
701 1 _aOzhereliev
_bO. A.
701 1 _aPestryakov
_bA. N.
_cChemist
_cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science
_f1963-
_gAleksey Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\30471
_4070
801 1 _aRU
_b63413507
_c20130326
801 2 _aRU
_b63413507
_c20130326
_gRCR
942 _cBK