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090 _a599242
100 _a20130429d2003 k y0engy50 ba
101 1 _aeng
102 _aRU
200 1 _aGallam-exchange separation of alkali metals
_fI. A. Tikhomirov, A. A. Orlov, D. G. Vidyaev
330 _aThe values of the coefficient of separation α of the alkali metals in the LiGa-NaOH, LiGa-KOH, and KGa-NaOH gallam-exchange systems were determined. The dependences of α on the temperature and concentrations of the phases involved in the exchange were studied for the LiGa-NaOH and LiGa-KOH systems. The kinetic parameters for the exchange of lithium, sodium, and potassium were obtained. The rate constants for the exchange of these elements were described by the Arrhenius equation. The corresponding values of the activation energy and integration constant were calculated. The separation and kinetic characteristics obtained were compared to the analogous parameters of amalgam-exchange systems. A gallam-exchange method for separating alkali metals was suggested.
333 _aВ фонде НТБ ТПУ отсутствует
461 _tRussian Journal of Physical Chemistry A
_d1930-
463 _tVol. 77, iss. 5
_vP. 841-843
_d2003
610 1 _aтруды учёных ТПУ
700 1 _aTikhomirov
_bI. A.
_cRussian Physicist
_cDoctor of Physical and Mathematical Sciences (DSc), Professor of the Department of General Physics of Tomsk Polytechnic University (TPU)
_f1921-2010
_gIvan Arsentyevich
_xTPU
_2stltpush
_3(RuTPU)RU\TPU\pers\30485
701 1 _aOrlov
_bA. A.
701 1 _aVidyaev
_bD. G.
801 1 _aRU
_b63413507
_c20100309
801 2 _aRU
_b63413507
_c20130429
_gRCR
942 _cBK