| 000 | 01978nam1a2200289 4500 | ||
|---|---|---|---|
| 001 | 599620 | ||
| 005 | 20231030033833.0 | ||
| 035 | _a(RuTPU)RU\TPU\tpu\23724 | ||
| 035 | _aRU\TPU\tpu\22912 | ||
| 090 | _a599620 | ||
| 100 | _a20130930a1988 k y0engy50 ba | ||
| 101 | 1 | _aeng | |
| 102 | _aRU | ||
| 200 | 1 |
_aStudy of catalyst activity in the extensive oxidation of butane and the state of platinum in lanthanum- and cerium-modified Pt/Al/sub 2/O/sub 3/ catalysts _fV. A. Drozdov [et al.] |
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| 330 | _aAn effect was demonstrated for the addition of lanthanum and cerium oxides to Pt/Al/sub 2/O/sub 3/ catalysts on the catalyst activity in the extensive oxidation of butane. Independently of the rate of the butane and oxygen concentrations in the gas phase, the specific catalyst activity (SCA) per m/sup 2/ Pt of the modified samples is less than that of the Pt/Al/sub 2/O/sub 3/ catalyst. The addition of lanthanum and cerium significantly increases the dispersion and stability of the supported platinum upon overheating. The IR spectra of the CO molecular probe were used to establish the electronic states of the surface platinum atoms in the samples studied after various treatments. In the presence of cerium oxide, platinum was found to undergo reduction with greater difficulty and have a greater tendency to undergo oxidation than platinum in the unmodified catalyst. | ||
| 333 | _aВ фонде НТБ ТПУ отсутствует | ||
| 461 |
_tKinetics and catalysis _d1960- |
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| 463 |
_tVol. 2, № 2 pt. 2 _vP. 420-423 _d1988 |
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| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aDrozdov _bV. A. |
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| 701 | 1 |
_aTsyrul'nikov _bP. G. |
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| 701 | 1 |
_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 _4070 |
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| 701 | 1 |
_aDavydov _bA. A. |
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| 701 | 1 |
_aPopvskii _bV. V. |
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| 801 | 1 |
_aRU _b63413507 _c20130226 |
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| 801 | 2 |
_aRU _b63413507 _c20130930 _gRCR |
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| 942 | _cBK | ||