000 | 01790nam0a2200289 4500 | ||
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001 | 602425 | ||
005 | 20231030033955.0 | ||
035 | _a(RuTPU)RU\TPU\tpu\28230 | ||
035 | _aRU\TPU\tpu\23158 | ||
090 | _a602425 | ||
100 | _a20160302d2002 k y0engy50 ba | ||
101 | 1 | _aeng | |
102 | _aRU | ||
105 | _ay z 000zy | ||
200 | 1 |
_aThe Preparation of the Lower Olefins from C3–C4 Alkaneson ZSM-5 Zeolites Modified by Lithium _fA. S. Trofimova, V. I. Erofeev, L. M. Koval’ |
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225 | 1 | _aChemical Kinetics and Catalysis | |
330 | _aThe influence of the method for modifying high-silica ZSM-5 zeolites by lithium on their acid and catalytic properties was studied by measuring the thermodesorption of ammonia and the catalytic conversion of C3–C4 alkanes. Modifying zeolites of this type by lithium was found to decrease their activity as a result of predominantly poisoning Broensted acid centers, to considerably increase selectivity with respect to ethylene and propylene, and to decrease the yield of arenes and the formation of coke deposits. The most effective method for the introduction of lithium into zeolites was mechanical mixing; the optimal amount of introduced lithium equaled 3%. | ||
333 | _aВ фонде НТБ ТПУ отсутствует | ||
461 |
_tRussian Journal of Physical Chemistry A _d1930- |
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463 |
_tVol. 76, iss. 6 _vP. 922-925 _d2002 |
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610 | 1 | _aтруды учёных ТПУ | |
700 | 1 |
_aTrofimova _bA. S. |
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701 | 1 |
_aErofeev _bV. I. _cspecialist in the field of oil and gas business _cProfessor of Tomsk Polytechnic University, Doctor of technical sciences _f1946- _gVladimir Ivanovich _2stltpush _3(RuTPU)RU\TPU\pers\32197 |
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701 | 1 |
_aKoval’ _bL. M. |
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801 | 1 |
_aRU _b63413507 _c20100309 |
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801 | 2 |
_aRU _b63413507 _c20160302 _gRCR |
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942 | _cBK |