000 01790nam0a2200289 4500
001 602425
005 20231030033955.0
035 _a(RuTPU)RU\TPU\tpu\28230
035 _aRU\TPU\tpu\23158
090 _a602425
100 _a20160302d2002 k y0engy50 ba
101 1 _aeng
102 _aRU
105 _ay z 000zy
200 1 _aThe Preparation of the Lower Olefins from C3–C4 Alkaneson ZSM-5 Zeolites Modified by Lithium
_fA. S. Trofimova, V. I. Erofeev, L. M. Koval’
225 1 _aChemical Kinetics and Catalysis
330 _aThe influence of the method for modifying high-silica ZSM-5 zeolites by lithium on their acid and catalytic properties was studied by measuring the thermodesorption of ammonia and the catalytic conversion of C3–C4 alkanes. Modifying zeolites of this type by lithium was found to decrease their activity as a result of predominantly poisoning Broensted acid centers, to considerably increase selectivity with respect to ethylene and propylene, and to decrease the yield of arenes and the formation of coke deposits. The most effective method for the introduction of lithium into zeolites was mechanical mixing; the optimal amount of introduced lithium equaled 3%.
333 _aВ фонде НТБ ТПУ отсутствует
461 _tRussian Journal of Physical Chemistry A
_d1930-
463 _tVol. 76, iss. 6
_vP. 922-925
_d2002
610 1 _aтруды учёных ТПУ
700 1 _aTrofimova
_bA. S.
701 1 _aErofeev
_bV. I.
_cspecialist in the field of oil and gas business
_cProfessor of Tomsk Polytechnic University, Doctor of technical sciences
_f1946-
_gVladimir Ivanovich
_2stltpush
_3(RuTPU)RU\TPU\pers\32197
701 1 _aKoval’
_bL. M.
801 1 _aRU
_b63413507
_c20100309
801 2 _aRU
_b63413507
_c20160302
_gRCR
942 _cBK