000 | 02080nlm1a2200373 4500 | ||
---|---|---|---|
001 | 639253 | ||
005 | 20231030040313.0 | ||
035 | _a(RuTPU)RU\TPU\network\3704 | ||
071 | 6 | 0 | _a10.1007/s10008-012-1727-2 |
090 | _a639253 | ||
100 | _a20150302a2012 k y0engy50 ba | ||
101 | 0 | _aeng | |
135 | _adrcn ---uucaa | ||
181 | 0 | _ai | |
182 | 0 | _ab | |
200 | 1 |
_aVoltammetric determination of cysteine at a graphite electrode modified with gold nanoparticles _fD. O. Perevezentseva, E. V. Gorchakov |
|
203 |
_aText _celectronic |
||
300 | _aTitle screen | ||
320 | _a[References: p. 2410 (25 tit.)] | ||
330 | _aThe electrochemical behaviour of cysteine (Cys) at a graphite electrode modified with gold nanoparticles (G-Aunano electrode) was studied by cyclic voltammetry. It was found that the graphite electrode-Au nanoparticles show an electrocatalytic activity towards the oxidation of Cys in 0.1 M NaOH. At 0.05 V, there is an “inverse” maximum in the cathodic voltammogram of Cys. Using a G-Aunano electrode, the dependence of the peak current of the “inverse” maximum on Cys concentration was linear in the range from 1 to 14 pM, and the detection limit was 0.6 pM. The proposed analytical method is simple, rapid and sensitive. | ||
333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
461 |
_tJournal of Solid State Electrochemistry _oScientific Journal |
||
463 |
_tVol. 16, iss. 7 _v[P. 2405-2410] _d2012 |
||
610 | 1 | _aэлектронный ресурс | |
610 | 1 | _aтруды учёных ТПУ | |
610 | 1 | _aCyclic voltammetry | |
610 | 1 | _aElectrocatalysis | |
610 | 1 | _aCysteine | |
610 | 1 | _aGold nanoparticles | |
700 | 1 |
_aPerevezentseva _bD. O. _cChemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1979- _gDariya Olegovna _2stltpush _3(RuTPU)RU\TPU\pers\33799 |
|
701 | 1 |
_aGorchakov _bE. V. |
|
801 | 2 |
_aRU _b63413507 _c20150302 _gRCR |
|
856 | 4 | _uhttp://link.springer.com/article/10.1007/s10008-012-1727-2 | |
942 | _cCF |