000 02080nlm1a2200373 4500
001 639253
005 20231030040313.0
035 _a(RuTPU)RU\TPU\network\3704
071 6 0 _a10.1007/s10008-012-1727-2
090 _a639253
100 _a20150302a2012 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aVoltammetric determination of cysteine at a graphite electrode modified with gold nanoparticles
_fD. O. Perevezentseva, E. V. Gorchakov
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 2410 (25 tit.)]
330 _aThe electrochemical behaviour of cysteine (Cys) at a graphite electrode modified with gold nanoparticles (G-Aunano electrode) was studied by cyclic voltammetry. It was found that the graphite electrode-Au nanoparticles show an electrocatalytic activity towards the oxidation of Cys in 0.1 M NaOH. At 0.05 V, there is an “inverse” maximum in the cathodic voltammogram of Cys. Using a G-Aunano electrode, the dependence of the peak current of the “inverse” maximum on Cys concentration was linear in the range from 1 to 14 pM, and the detection limit was 0.6 pM. The proposed analytical method is simple, rapid and sensitive.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Solid State Electrochemistry
_oScientific Journal
463 _tVol. 16, iss. 7
_v[P. 2405-2410]
_d2012
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aCyclic voltammetry
610 1 _aElectrocatalysis
610 1 _aCysteine
610 1 _aGold nanoparticles
700 1 _aPerevezentseva
_bD. O.
_cChemist
_cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences
_f1979-
_gDariya Olegovna
_2stltpush
_3(RuTPU)RU\TPU\pers\33799
701 1 _aGorchakov
_bE. V.
801 2 _aRU
_b63413507
_c20150302
_gRCR
856 4 _uhttp://link.springer.com/article/10.1007/s10008-012-1727-2
942 _cCF