| 000 | 01926nlm1a2200337 4500 | ||
|---|---|---|---|
| 001 | 639880 | ||
| 005 | 20231030040333.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\4393 | ||
| 090 | _a639880 | ||
| 100 | _a20150330a2011 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aSynthesis and oxidation of some azole-containing thioethers _fA. S. Potapov [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 25 tit.] | ||
| 330 | _aPyrazole and benzotriazole-containing thioethers, namely 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-thiapentane, 1,8-bis(3,5-dimethylpyrazol-1-yl)-3,6-dithiaoctane and 1,3-bis(1,2,3-benzotriazol-1-yl)-2-thiapropane were prepared and fully characterized. Oxidation of the pyrazole-containing thioether by hydrogen peroxide proceeds selectively to provide a sulfoxide or sulfone, depending on the amount of oxidant used. Oxidation of the benzotriazole derivative by hydrogen peroxide is not selective, and sulfoxide and sulfone form concurrently. Selenium dioxide-catalyzed oxidation of benzotriazole thioether by H2O2, however, proceeds selectively and yields sulfoxide only. | ||
| 461 |
_tBeilstein Journal of Organic Chemistry _oScientific Journal _d2005- |
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| 463 |
_tVol. 7 _v[P. 1526-1532] _d2011 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aPotapov _bA. S. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1981- _gAndrey Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\33909 |
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| 701 | 1 |
_aChernova _bN. P. |
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| 701 | 1 |
_aOgorodnikov _bV. D. |
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| 701 | 1 |
_aPetrenko _bT. V. |
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| 701 | 1 |
_aKhlebnikov _bA. I. _cChemist _cProfessor of Tomsk Polytechnic University _f1963- _gAndrey Ivanovich _2stltpush _3(RuTPU)RU\TPU\pers\33927 |
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| 801 | 2 |
_aRU _b63413507 _c20170321 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.3762/bjoc.7.179 | |
| 942 | _cCF | ||