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035 _a(RuTPU)RU\TPU\network\5374
035 _aRU\TPU\network\5373
090 _a640783
100 _a20150425a2009 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aOn the high resolution spectroscopy and intramolecular potential function of SO2
_fO. N. Ulenikov [at al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 156 (46 tit.)]
330 _aTwo weak stretching bands, ν1 + 3ν3 and 3ν1 + ν3, of the sulfur dioxide molecule have been recorded at high resolution and analyzed for the first time with using a Fourier transform Bruker IFS-120 HR interferometer. About 1000 transitions with Jmax. = 51, K max/a = 16, and 900 transitions with Jmax. = 53, K max/a = 16 have been assigned to the bands ν1 + 3ν3 and 3ν1 + ν3, respectively. Analysis of the recorded spectra was made using the model of isolated vibrational states. Parameters obtained from the fit reproduce the initial experimental ro-vibrational energies with the rms deviation of 0.0006 and 0.0012 cm−1for the bands, 3ν1 + ν3 and ν1 + 3ν3, respectively. The problem of determination of the intramolecular potential function of SO2 is discussed.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Molecular Spectroscopy
_oScientific Journal
463 _tVol. 257, iss. 2
_v[P. 137–156]
_d2009
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aAlanko
_bS.
701 1 _aHorneman
_bV.-M.
701 1 _aGromova
_bO. V.
_cphysicist
_cEngineer-Researcher of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1982-
_gOlga Vasilievna
_2stltpush
_3(RuTPU)RU\TPU\pers\34333
701 1 _aLeroy
_bK. A.
_cphysicist
_cJunior researcher at Tomsk Polytechnic University, candidate of physico-mathematical Sciences
_cProfessor, University of Montreal (France)
_f1961-
_gKlod (Claude) Andre
_2stltpush
_3(RuTPU)RU\TPU\pers\37958
801 2 _aRU
_b63413507
_c20171003
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.jms.2009.07.005
942 _cCF