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182 0 _ab
200 1 _aOn the local mode behaviour of the XH2/XD2 and XD/XH fragments with respect to the deuterated species of the near local mode XH3(C3v ) molecule
_fO. N. Ulenikov, E. S. Bekhtereva, C. Leroy
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 1415 (15 tit.)]
330 _aEffect of isotopic substitution in the near local mode, XH3(C3v ), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3(C3v ) molecule with the value of interbond angle close to п/2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode ‘molecule’ XH2/XD2 and of a diatomic XD/XH ‘molecule’. The phosphine molecule is considered as an illustration.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tMolecular Physics
_oAn International Journal at the Interface Between Chemistry and Physics
463 _tVol. 107, iss. 14
_v[P. 1409-1416]
_d2009
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
700 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aLeroy
_bK. A.
_cphysicist
_cJunior researcher at Tomsk Polytechnic University, candidate of physico-mathematical Sciences
_cProfessor, University of Montreal (France)
_f1961-
_gKlod (Claude) Andre
_2stltpush
_3(RuTPU)RU\TPU\pers\37958
801 2 _aRU
_b63413507
_c20171003
_gRCR
856 4 _uhttp://dx.doi.org/10.1080/00268970902905828
942 _cCF