| 000 | 03083nlm1a2200385 4500 | ||
|---|---|---|---|
| 001 | 640787 | ||
| 005 | 20231030040406.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\5378 | ||
| 035 | _aRU\TPU\network\5377 | ||
| 090 | _a640787 | ||
| 100 | _a20150425a2010 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aGB | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aHigh resolution infrared spectroscopy and global vibrational analysis for the CH3D and CHD3 isotopomers of methane _fO. N. Ulenikov [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: p. 1238-1240 (83 tit.)] | ||
| 330 | _aWe report infrared spectra of CH3D and CHD3 in the range 2900 to 9000 cm−1 measured with the Zürich high resolution Fourier transform infrared (FTIR) interferometer Bruker IFS 125 prototype (ZP 2001) at 80 K in a collisional-cooling cell with optical paths ranging from 5 to 10 m. In all, 57 new ro-vibrational bands of CH3D and 40 for CHD3 were assigned and analysed. Using a strategy of the direct assignment of the J = 0 states of excited vibrational levels, precise experimental values of the band centres with uncertainties in the range of about 0.0001 to 0.0003 cm−1 were obtained. Including 15 previously known band centres of CH3D and 12 previously known band centres of CHD3, these data were used as the initial information for the determination of the harmonic frequencies, anharmonic coefficients, and vibrational resonance interaction parameters in an effective hamiltonian. A joint set of 64 parameters reproduces the 124 experimental vibrational energies of both molecules up to 6500 cm−1 with a root mean deviation of d rms= 0.73 cm−1. The results are discussed in relation to intramolecular dynamics on a global potential hypersurface of methane, intramolecular vibrational redistribution, and the spectroscopy of the atmospheres of the earth and planetary systems. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tMolecular Physics _oAn International Journal at the Interface Between Chemistry and Physics |
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| 463 |
_tVol. 108, iss. 7-9 _v[P. 1209-1240] _d2010 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aUlenekov (Ulenikov) _bO. N. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1949- _gOleg Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\34331 |
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| 701 | 1 |
_aBekhtereva _bE. S. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1974- _gElena Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\34450 |
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| 701 | 1 |
_aAlbert _bS. |
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| 701 | 1 |
_aBauerecker _bZ. (S.) H. _cphysicist _cJunior researcher at Tomsk Polytechnic University _f1960- _gZigurd (Sigurd) Hermann _2stltpush _3(RuTPU)RU\TPU\pers\37573 |
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| 701 | 1 |
_aHollenstein _bH. |
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| 701 | 1 |
_aQuack _bM. |
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| 801 | 2 |
_aRU _b63413507 _c20171003 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1080/00268976.2010.483131 | |
| 942 | _cCF | ||