| 000 | 03039nlm1a2200373 4500 | ||
|---|---|---|---|
| 001 | 640793 | ||
| 005 | 20231030040406.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\5384 | ||
| 035 | _aRU\TPU\network\5378 | ||
| 090 | _a640793 | ||
| 100 | _a20150425a2010 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aGB | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aOn the "expanded local mode" approach applied to the methane molecule: isotopic substitution CH2D2 ←CH4 _fO. N. Ulenikov [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: p. 2127-2128 (47 tit.)] | ||
| 330 | _aOn the basis of a compilation of the ‘expanded local mode’ model and the general isotopic substitution theory, sets of simple analytical relations between different spectroscopic parameters (harmonic frequencies, ωλ anharmonic coefficients, χλμ, ro-vibrational coefficients, αβλ, different kinds of Fermi- and Coriolis-type interaction parameters) of the CH2D2 molecule are derived. All of them are expressed as simple functions of a few initial spectroscopic parameters of the mother, CH4, molecule. Test calculations with the derived isotopic relations show that, in spite of a total absence of initial information about the CH2D2 species, the numerical results of the calculations have a very good correlation both with experimental data, and results of ab initio calculations. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tMolecular Physics _oAn International Journal at the Interface Between Chemistry and Physics |
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| 463 |
_tVol. 109, iss. 17-18: 22nd Colloquium on High-Resolution Molecular Spectroscopy HRMS Dijon 2011 (Part 1): dedicated to Gianfranco Di Lonardo _v[P. 2111-2130] _d2010 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aUlenekov (Ulenikov) _bO. N. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1949- _gOleg Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\34331 |
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| 701 | 1 |
_aFomchenko _bA. L. _cphysicist _cAssistant of Tomsk Polytechnic University _f1987- _gAnna Leonidovna _2stltpush _3(RuTPU)RU\TPU\pers\34089 |
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| 701 | 1 |
_aBekhtereva _bE. S. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1974- _gElena Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\34450 |
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| 701 | 1 |
_aGromova _bO. V. _cphysicist _cEngineer-Researcher of Tomsk Polytechnic University, Candidate of physical and mathematical sciences _f1982- _gOlga Vasilievna _2stltpush _3(RuTPU)RU\TPU\pers\34333 |
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| 701 | 1 |
_aLeroy _bK. A. _cphysicist _cJunior researcher at Tomsk Polytechnic University, candidate of physico-mathematical Sciences _cProfessor, University of Montreal (France) _f1961- _gKlod (Claude) Andre _2stltpush _3(RuTPU)RU\TPU\pers\37958 |
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| 801 | 2 |
_aRU _b63413507 _c20171003 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1080/00268976.2011.611479 | |
| 942 | _cCF | ||