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| 001 | 641652 | ||
| 005 | 20231030040435.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\6569 | ||
| 090 | _a641652 | ||
| 100 | _a20150526a2015 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aPrecise ro-vibrational analysis of molecular bands forbidden in absorption: The ν8+ν10 band of the 12C2H4 molecule _fO. N. Ulenikov [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: p. 13 (52 tit.)] | ||
| 330 | _aThe highly accurate (experimental accuracy in line positions ð1 2Þ 104 cm1 ) ro-vibrational spectrum of the m8 þ m10 band of the 12C2H4 molecule was recorded for the first time with high resolution Fourier transform spectrometry and analyzed in the region of 1650-1950 cm1 using the Hamiltonian model which takes into account Coriolis resonance interactions between the studied m8 þ m10 band, which is forbidden in absorption, and the bands m4 þ m8 and m7 þ m8. About 1570 transitions belonging to the m8 þ m10 band were assigned in the experimental spectra with the maximum values of quantum numbers J max: ¼ 35 and Kmax: a ¼ 18. On that basis, a set of 38 vibrational, rotational, centrifugal distortion, and resonance interaction parameters was obtained from the fit. They reproduce values of 598 initial ''experimental'' ro-vibrational energy levels (positions of about 1570 experimentally recorded and assigned transitions) with the rms error drms ¼ 0:00045 cm1 (drms ¼ 0:00028 cm1 when upper ro-vibrational energies obtained from blended and very weak transitions were deleted from the fit). | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tJournal of Molecular Spectroscopy _oScientific Journal |
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| 463 |
_tVol. 313 _v[P. 4–13] _d2015 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aUlenekov (Ulenikov) _bO. N. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1949- _gOleg Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\34331 |
|
| 701 | 1 |
_aGromova _bO. V. _cphysicist _cEngineer-Researcher of Tomsk Polytechnic University, Candidate of physical and mathematical sciences _f1982- _gOlga Vasilievna _2stltpush _3(RuTPU)RU\TPU\pers\34333 |
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| 701 | 1 |
_aBekhtereva _bE. S. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1974- _gElena Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\34450 |
|
| 701 | 1 |
_aKashirina _bN. V. _cchemist-technologist _cTechnician of Tomsk Polytechnic University _f1993- _gNadezhda Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\32325 |
|
| 701 | 1 |
_aBauerecker _bZ. (S.) H. _cphysicist _cJunior researcher at Tomsk Polytechnic University _f1960- _gZigurd (Sigurd) Hermann _2stltpush _3(RuTPU)RU\TPU\pers\37573 |
|
| 701 | 1 |
_aHorneman _bV.-M. |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bФизико-технический институт (ФТИ) _bКафедра общей физики (ОФ) _h136 _2stltpush _3(RuTPU)RU\TPU\col\18734 |
| 801 | 2 |
_aRU _b63413507 _c20171003 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1016/j.jms.2015.04.008 | |
| 942 | _cCF | ||