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035 _a(RuTPU)RU\TPU\network\7576
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100 _a20150630a1994 k y0engy50 ba
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102 _aGB
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aLine positions and intensities of the v1+2v2+v3 and 2v2+2v3 of 16O3
_fS. Bouazza [et al.]
203 _aText
_celectronic
300 _aTitle screen
330 _aA study of high-resolution (0.006 cm−1) Fourier transform absorption spectra of 16O3around 3450 cm−1 has been performed, leading to the first analysis of the ν1 + 2ν2 + ν3 and 2ν2 + 2ν3 bands of this molecule. To increase the absorption strength of these very weak bands a White cell with path lengths of up to 36 m and pressures from 40 to 55 Torr was used. The rotational energy levels of the (121) and (022) vibrational states deduced from observed spectra have been satisfactorily reproduced using a Hamiltonian matrix which takes explicitly into account the Coriolis interaction between (121) ↔ (022) and (121) ↔ (220) and Darling-Dennison interaction between (022) ↔ (220). Furthermore about 60 and 20 line intensities, respectively, for the (121) and (022) bands were measured with an accuracy of about 6 and 12%, leading to the determination of the ν1 + 2ν2 + ν3 and 2ν2 + 2ν3 vibrational transition moments. Finally, a complete list of line positions, intensities, and lower state energies for both bands has been generated.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Molecular Structureer
_d1957-
463 _tVol. 166, № 2
_v[P. 365–371]
_d1994
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aBouazza
_bS.
701 1 _aBarbe
_bA.
701 1 _aMikhailenko
_bS. N.
_cphysicist
_cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1962-
_gSemen Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34035
701 1 _aPlateaux
_bJ. J.
801 2 _aRU
_b63413507
_c20160412
_gRCR
856 4 _uhttp://dx.doi.org/10.1006/jmsp.1994.1201
942 _cCF