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101 0 _aeng
135 _adrnn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aFerroelectric polymer scaffolds based on a copolymer of tetrafluoroethylene with vinylidene fluoride: Fabrication and properties
_fE. N. Bolbasov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 41 (46 tit.)]
330 _aA solution blow spinning technique is a method developed recently for making nonwoven webs of micro- and nanofibres. The principal advantage of this method compared to a more traditional electrospinning process is its significantly higher production rate. In this work, the solution blow spinning method was further developed to produce nonwoven polymeric scaffolds based on a copolymer of tetrafluoroethylene with vinylidene fluoride solution in acetone. A crucial feature of the proposed method is that high-voltage equipment is not required, which further improves the method's economics. Scanning electron microscopy analysis of the samples demonstrated that the surface morphology of the nonwoven materials is dependent on the polymer concentration in the spinning solution. It was concluded that an optimum morphology of the nonwoven scaffolds for medical applications is achieved by using a 5% solution of the copolymer. It was established that the scaffolds produced from the 5% solution have a fractal structure and anisotropic mechanical properties. X-ray diffraction, infrared spectroscopy, Raman spectroscopy and differential scanning calorimetry demonstrated that the fabricated nonwoven materials have crystal structures that exhibit ferroelectric properties. Gas chromatography has shown that the amount of acetone in the nonwoven material does not exceed the maximum allowable concentration of 0.5%. In vitro analysis, using the culture of motile cells, confirmed that the nonwoven material is non-toxic and does not alter the morpho-functional status of stem cells for short-term cultivation, and therefore can potentially be used in medical applications.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tMaterials Science and Engineering: C
463 _tVol. 40
_v[P. 32-41]
_d2014
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aBolbasov
_bE. N.
_cphysicist
_cEngineer of Tomsk Polytechnic University
_f1981-
_gEvgeny Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\30857
701 1 _aAnissimov
_bY. G.
701 1 _aPustovoytov
_bA. V.
701 1 _aKhlusov
_bI. A.
_cbiophysicist
_cProfessor of Tomsk Polytechnic University, doctor of medical Sciences
_f1963-
_gIgor Albertovich
_2stltpush
_3(RuTPU)RU\TPU\pers\34907
701 1 _aZaitsev
_bA. A.
701 1 _aZaitsev
_bK. V.
701 1 _aLapin
_bI. N.
701 1 _aTverdokhlebov
_bS. I.
_cphysicist
_cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical science
_f1961-
_gSergei Ivanovich
_2stltpush
_3(RuTPU)RU\TPU\pers\30855
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bФизико-технический институт (ФТИ)
_bКафедра теоретической и экспериментальной физики (ТиЭФ)
_h138
_2stltpush
_3(RuTPU)RU\TPU\col\18726
801 2 _aRU
_b63413507
_c20160603
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.msec.2014.03.038
942 _cCF