| 000 | 03186nla2a2200433 4500 | ||
|---|---|---|---|
| 001 | 643022 | ||
| 005 | 20231030040522.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\8010 | ||
| 035 | _aRU\TPU\network\8008 | ||
| 090 | _a643022 | ||
| 100 | _a20150827a2015 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aGB | ||
| 105 | _ay z 100zy | ||
| 135 | _adrgn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aSimultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys _fE. V. Larionova, K. A. Bulygina |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 24 tit.] | ||
| 330 | _aIn this work the possibility of simultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys with help of the mixed organic reagents (diphenylcarbazide and 1,10-phenanthroline, diphenylcarbazide and sulphosalicylic acid) is studied. We have applied curve fitting method to separate individual signals of chromium (VI) and iron (III) from overlapped absorption spectrum. Peak shape analysis of pure signals of complexes of chromium (VI) with diphenylcarbazide and iron (III) with the 1,10-phenanthroline and sulphosalicylic acid is previously carried out. For adequate application of curve fitting method we chose the optimal empirical models of signals taking into account preliminary information on their shape. Correctness of determination of concentration by means of the offered technique is proved by "added-found" method for a series of mixtures with different ratios of concentration of chromium (VI) and iron (III). It is founded that the error of determination of concentration doesn't exceed 11%. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 337 | _aAdobe Reader | ||
| 461 | 1 |
_0(RuTPU)RU\TPU\network\2008 _tIOP Conference Series: Materials Science and Engineering |
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| 463 | 1 |
_0(RuTPU)RU\TPU\network\7891 _tVol. 81 : Radiation-Thermal Effects and Processes in Inorganic Materials _oInternational Scientific Conference, 3-8 November 2014, Tomsk, Russia _o[proceedings] _v[012093, 6 p.] _d2015 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aхром | |
| 610 | 1 | _aжелезо | |
| 610 | 1 | _aсплавы | |
| 610 | 1 | _aспектрофотометрическое определение | |
| 700 | 1 |
_aLarionova _bE. V. _cchemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1978- _gEkaterina Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\35096 |
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| 701 | 1 |
_aBulygina _bK. A. |
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| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут неразрушающего контроля (ИНК) _bКафедра экологии и безопасности жизнедеятельности (ЭБЖ) _h4850 _2stltpush _3(RuTPU)RU\TPU\col\18720 |
| 801 | 2 |
_aRU _b63413507 _c20161212 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1088/1757-899X/81/1/012093 | |
| 856 | 4 | _uhttp://earchive.tpu.ru/handle/11683/14736 | |
| 942 | _cCF | ||