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101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aRuthenium pincer complexes: Ligand design and complex synthesis
_fH. A. Yo. Hassan [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 151-152 (270 tit.)]
330 _aActive transition–metal complexes basedonrelatively inexpensivemetals are consideredto be adesirablemethod for sustainable human industrial growth. Considering their cost efficiency, ruthenium complexesare gaining increasing attraction, instead of palladium, rhodium, and iridium. Among the rutheniumcomplexes, ruthenium pincer complexes (RPCs) have received much attention due to their outstandingperformance. Various strategies have been developed for pincer ligand design and RPC synthesis, whichindicate that ligand design is a key feature of pincer chemistry. In addition, electronic and steric effects, hemilability, non-innocent behavior, and the flexibility of the pincer ligand have significant effects on thecatalytic performance of RPCs in hydrogenation and dehydrogenation reactions.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tCoordination Chemistry Reviews
_oScientific Journal
463 _tVol. 276
_v[P. 112–152]
_d2015
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aHassan
_bH. A. Yo.
_cchemical engineer
_cassistant of Tomsk Polytechnic University
_f1985-
_gHussein Abdelazeem Younus
_2stltpush
_3(RuTPU)RU\TPU\pers\39720
701 1 _aAhmad
_bN.
_cchemical engineer
_cassistant of Tomsk Polytechnic University
_f1981-
_gNazir
_2stltpush
_3(RuTPU)RU\TPU\pers\39722
701 0 _aSu Wei
701 1 _aVerpoort
_bF. V. K.
_cchemist-technologist
_cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences
_f1963-
_gFrensis Valter Kornelius
_2stltpush
_3(RuTPU)RU\TPU\pers\35059
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут природных ресурсов (ИПР)
_bКафедра технологии органических веществ и полимерных материалов (ТОВПМ)
_h6832
_2stltpush
_3(RuTPU)RU\TPU\col\18659
801 2 _aRU
_b63413507
_c20171027
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.ccr.2014.06.016
942 _cCF