| 000 | 03385nlm0a2200469 4500 | ||
|---|---|---|---|
| 001 | 644103 | ||
| 005 | 20231030040608.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\9151 | ||
| 035 | _aRU\TPU\network\6911 | ||
| 090 | _a644103 | ||
| 100 | _a20151028a2015 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aRU | ||
| 105 | _ay z 000zy | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aInfluence of the content of Mn²⁺ on the phase composition of the precursor of MnO x -Al₂O₃ catalyst and the catalytic activity in the oxidation reaction of methane _fS. I. Galanov [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 980-981 (22 tit.)] | ||
| 330 | _aThe influence of the concentration of Mn2+ in a solution for the hydrolysis of nanosized aluminum powder on the phase composition of the precursor and the content of manganese in samples of aluminum hydroxide is studied. Stages of the formation of catalysts from the precursors are studied by means of synchronic thermogravimetric (TG)-differential scanning calorimetry (DSC) analysis and X-ray phase analysis (XPA). The influence of the number of manganese ions in aluminum hydroxide on the phase composition and catalytic properties of MnO x -Al2O3 systems in the reaction of the deep oxidation of methane is also studied. It is shown that an increase in the concentration of manganese ions in the solution for hydrolysis raises the content of unreacted aluminum and X-ray amorphous hydroxides in the precursors of the catalysts. It is established that the phase composition of the catalyst and the catalytic activity in the reaction of the deep oxidation of methane depend on the content of manganese in the precursor. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tRussian Journal of Physical Chemistry A _oScientific Journal _d1930- |
||
| 463 |
_tVol. 89, iss. 6 _v[P. 974-981] _d2015 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aкатализаторы | |
| 610 | 1 | _aфазовый состав | |
| 610 | 1 | _aтермогравиметрический анализ | |
| 610 | 1 | _aкаталитические свойства | |
| 610 | 1 | _aметан | |
| 610 | 1 | _aокисление | |
| 701 | 1 |
_aGalanov _bS. I. |
|
| 701 | 1 |
_aSidorova _bO. I. |
|
| 701 | 1 |
_aGryaznova _bE. N. _cchemical engineer _cEngineer-researcher of Tomsk Polytechnic University _f1987- _gElena Nikolaevna _2stltpush _3(RuTPU)RU\TPU\pers\31929 |
|
| 701 | 1 |
_aShiyan _bL. N. _cchemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences _f1952- _gLyudmila Nikolaevna _2stltpush _3(RuTPU)RU\TPU\pers\31523 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bОтдел организации НИОКР _c(2009- ) |
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bКафедра общей химии и химической технологии _c(2009- ) |
| 801 | 2 |
_aRU _b63413507 _c20151028 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1134/S0036024415060102 | |
| 942 | _cCF | ||