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035 _a(RuTPU)RU\TPU\network\9303
090 _a644238
100 _a20151106a2015 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aRo-vibrational analysis of the hot bands of 13C2H4: ν7+ν10-ν10 and ν10+ν12-ν10
_fO. N. Ulenikov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 39-40 (57 tit.)]
330 _aTwo “hot” absorption bands, ν7+ν10-ν10 and ν10+ν12-ν10, of 13C2H4 were recorded for the first time with a Bruker high resolution Fourier transform spectrometer and theoretically analyzed. About 640 and 270 transitions (168 and 136 upper state ro-vibrational energy values) with and for the bands ν7+ν10-ν10 and ν10+ν12-ν10, respectively, were assigned. For that purpose strong local resonance interactions with ten other closely located vibrational states were taken into account. A set of 36 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 6.7×10-4 cm and which is close to experimental uncertainties.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Molecular Spectroscopy
_oScientific Journal
463 _tVol. 317
_v[P. 32-40]
_d2015
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aэтилен
610 1 _aразрешение
610 1 _aспектры
610 1 _aспектроскопические параметры
701 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aGromova
_bO. V.
_cphysicist
_cEngineer-Researcher of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1982-
_gOlga Vasilievna
_2stltpush
_3(RuTPU)RU\TPU\pers\34333
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aKashirina
_bN. V.
_cchemist-technologist
_cTechnician of Tomsk Polytechnic University
_f1993-
_gNadezhda Vladimirovna
_2stltpush
_3(RuTPU)RU\TPU\pers\32325
701 1 _aOnopenko
_bG. A.
_gGalina Aleksandrovna
701 1 _aBauerecker
_bZ. (S.) H.
_cphysicist
_cJunior researcher at Tomsk Polytechnic University
_f1960-
_gZigurd (Sigurd) Hermann
_2stltpush
_3(RuTPU)RU\TPU\pers\37573
701 1 _aMaul
_bC.
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bФизико-технический институт (ФТИ)
_bКафедра общей физики (ОФ)
_h136
_2stltpush
_3(RuTPU)RU\TPU\col\18734
801 2 _aRU
_b63413507
_c20171003
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.jms.2015.08.010
942 _cCF