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100 _a20151111a2015 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aMetal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations
_fA. H. Chughtai [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 6842-6849 (315 tit.)]
330 _aNovel catalytic materials are highly demanded to perform a variety of catalytic organic reactions. MOFs combine the benefits of heterogeneous catalysis like easy post reaction separation, catalyst reusability, high stability and homogeneous catalysis such as high efficiency, selectivity, controllability and mild reaction conditions. The possible organization of active centers like metallic nodes, organic linkers, and their chemical synthetic functionalization on the nanoscale shows potential to build up MOFs particularly modified for catalytic challenges. In this review, we have summarized the recent research progress in heterogeneous catalysis by MOFs and their catalytic behavior in various organic reactions, highlighting the key features of MOFs as catalysts based on the active sites in the framework. Examples of their post functionalization, inclusion of active guest species and metal nanoparticles have been discussed. Finally, the use of MOFs as catalysts for asymmetric heterogeneous catalysis and stability of MOFs has been presented as separate sections.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tChemical Society Reviews
463 _tVol. 44, iss. 19
_v[P. 6804-6849]
_d2015
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aChughtai
_bA. H.
_gAdeel
701 1 _aAhmad
_bN.
_cchemical engineer
_cassistant of Tomsk Polytechnic University
_f1981-
_gNazir
_2stltpush
_3(RuTPU)RU\TPU\pers\39722
701 1 _aHassan
_bH. A. Yo.
_cchemical engineer
_cassistant of Tomsk Polytechnic University
_f1985-
_gHussein Abdelazeem Younus
_2stltpush
_3(RuTPU)RU\TPU\pers\39720
701 1 _aLyapkov
_bA. A.
_cChemical-technologist
_cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences
_f1958-
_gAleksey Alekseevich
_2stltpush
_3(RuTPU)RU\TPU\pers\31997
701 1 _aVerpoort
_bF. V. K.
_cchemist-technologist
_cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences
_f1963-
_gFrensis Valter Kornelius
_2stltpush
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712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут природных ресурсов (ИПР)
_bКафедра технологии органических веществ и полимерных материалов (ТОВПМ)
_h6832
_2stltpush
_3(RuTPU)RU\TPU\col\18659
801 2 _aRU
_b63413507
_c20171027
_gRCR
856 4 _uhttp://dx.doi.org/10.1039/C4CS00395K
942 _cCF