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100 | _a20151111a2015 k y0engy50 ba | ||
101 | 0 | _aeng | |
135 | _adrcn ---uucaa | ||
181 | 0 | _ai | |
182 | 0 | _ab | |
200 | 1 |
_aMetal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations _fA. H. Chughtai [et al.] |
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203 |
_aText _celectronic |
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300 | _aTitle screen | ||
320 | _a[References: p. 6842-6849 (315 tit.)] | ||
330 | _aNovel catalytic materials are highly demanded to perform a variety of catalytic organic reactions. MOFs combine the benefits of heterogeneous catalysis like easy post reaction separation, catalyst reusability, high stability and homogeneous catalysis such as high efficiency, selectivity, controllability and mild reaction conditions. The possible organization of active centers like metallic nodes, organic linkers, and their chemical synthetic functionalization on the nanoscale shows potential to build up MOFs particularly modified for catalytic challenges. In this review, we have summarized the recent research progress in heterogeneous catalysis by MOFs and their catalytic behavior in various organic reactions, highlighting the key features of MOFs as catalysts based on the active sites in the framework. Examples of their post functionalization, inclusion of active guest species and metal nanoparticles have been discussed. Finally, the use of MOFs as catalysts for asymmetric heterogeneous catalysis and stability of MOFs has been presented as separate sections. | ||
333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
461 | _tChemical Society Reviews | ||
463 |
_tVol. 44, iss. 19 _v[P. 6804-6849] _d2015 |
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610 | 1 | _aэлектронный ресурс | |
610 | 1 | _aтруды учёных ТПУ | |
701 | 1 |
_aChughtai _bA. H. _gAdeel |
|
701 | 1 |
_aAhmad _bN. _cchemical engineer _cassistant of Tomsk Polytechnic University _f1981- _gNazir _2stltpush _3(RuTPU)RU\TPU\pers\39722 |
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701 | 1 |
_aHassan _bH. A. Yo. _cchemical engineer _cassistant of Tomsk Polytechnic University _f1985- _gHussein Abdelazeem Younus _2stltpush _3(RuTPU)RU\TPU\pers\39720 |
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701 | 1 |
_aLyapkov _bA. A. _cChemical-technologist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1958- _gAleksey Alekseevich _2stltpush _3(RuTPU)RU\TPU\pers\31997 |
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701 | 1 |
_aVerpoort _bF. V. K. _cchemist-technologist _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
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712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
801 | 2 |
_aRU _b63413507 _c20171027 _gRCR |
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856 | 4 | _uhttp://dx.doi.org/10.1039/C4CS00395K | |
942 | _cCF |