| 000 | 02632nlm1a2200385 4500 | ||
|---|---|---|---|
| 001 | 644435 | ||
| 005 | 20231030040619.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\9516 | ||
| 090 | _a644435 | ||
| 100 | _a20151117a2015 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aOxygen-chelated indenylidene ruthenium catalysts for olefin metathesis _fXie Yu [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 579 (55 tit.)] | ||
| 330 | _aOlefin metathesis is a transition metal-mediated transformation that rearranges the carbon atoms of the carbon–carbon double bond of olefins. This reaction has become one of the most important and powerful reactions. Therefore development of new, well-defined, highly active and selective catalysts is very desirable and a valuable goal. This mini-review mainly introduces the development of ruthenium catalysts in olefin metathesis highlighting oxygen-chelated indenylidene ruthenium catalysts. Applying an alkoxyl group on the indenylidene ligand fragment can generate the Ru[BOND]O chelating bond. Additionally, various modifications of the ligand as well as the catalytic activity for ring-closing metathesis reaction and selectivity of cross metathesis reaction are overviewed. Finally, the perspectives on the development of new catalysts are summarized. | ||
| 461 | _tApplied Organometallic Chemistry | ||
| 463 |
_tVol. 29, iss. 9 _v[P. 573-579] _d2015 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 0 | _aXie Yu | |
| 701 | 0 | _aYuan Ye | |
| 701 | 1 |
_aMousavi _bB. _gBibimaryam |
|
| 701 | 0 | _aYuan Cai | |
| 701 | 0 | _aCheng Kai | |
| 701 | 0 | _aYin Lu | |
| 701 | 1 |
_aYusubov _bM. S. _cchemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1961- _gMekhman Suleiman-Ogly (Suleimanovich) _2stltpush _3(RuTPU)RU\TPU\pers\31833 |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cchemist-technologist _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
| 801 | 2 |
_aRU _b63413507 _c20160418 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1002/aoc.3338 | |
| 942 | _cCF | ||