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100 _a20151125a2015 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aPulsed Corona Discharge in Water Treatment: The Effect of Hydrodynamic Conditions on Oxidation Energy Efficiency
_fP. Ajo, Ya. I. Kornev, S. Preis
203 _aText
_celectronic
300 _aTitle screen
330 _aWater treatment by gas-phase pulsed corona discharge (PCD) relies mainly on utilization of ozone and OH radicals as oxidizing agents. In a configuration where the treated solution is showered through the plasma zone, the gas–liquid contact surface is the primary OH-radical formation site and the interface in the mass transfer of ozone. Its significance to overall process efficiency is therefore notable. In this study, the effect of varying contact surface area at different discharge powers was investigated from the perspective of efficient utilization of the two prime oxidants in slow reaction with oxalate. It is seen that increasing the area of the contact surface improves OH-radical utilization up to the point where the pollutant oxidation efficiency abruptly decreases presumably because of unfavorable pulse energy distribution in the gas–liquid mixture. The existence of an optimal area for a given power has implications for future studies in the design of pulsed plasma applications for water treatment.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tIndustrial & Engineering Chemistry Research
463 _tVol. 54 (30)
_v[P. 7452-7458]
_d2015
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
700 1 _aAjo
_bP.
_gPetri
701 1 _aKornev
_bYa. I.
_cspecialist in the field of electrical engineering
_csenior research fellow at the Tomsk Polytechnic University, candidate of technical Sciences
_f1976-
_gYakov Ivanovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33300
701 1 _aPreis
_bS.
_cspecialist in the field of materials science
_cProfessor of Tomsk Polytechnic University, candidate of technical Sciences
_f1959-
_gSergei
_2stltpush
_3(RuTPU)RU\TPU\pers\35690
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут физики высоких технологий (ИФВТ)
_bКафедра материаловедения и технологии металлов (МТМ)
_h73
_2stltpush
_3(RuTPU)RU\TPU\col\18689
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут физики высоких технологий (ИФВТ)
_bЛаборатория № 12
_h6389
_2stltpush
_3(RuTPU)RU\TPU\col\19054
801 2 _aRU
_b63413507
_c20190327
_gRCR
856 4 _uhttp://dx.doi.org/10.1021/acs.iecr.5b01915
942 _cCF