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005 20231030040630.0
035 _a(RuTPU)RU\TPU\network\9851
035 _aRU\TPU\network\9303
090 _a644767
100 _a20151130a2015 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aHigh resolution FTIR study of 34S16O2: The bands 2ν3,2ν1+ν2 and 2ν1+ν2-ν2
_fO. N. Ulenikov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 11-14 (48 tit.)]
330 _aThe high resolution infrared spectrum of the 34S16O2 molecule was recorded in the region of 2600-2810 cm−1 where the strong 2ν3 band is located. About 2500 transitions with maximum values of quantum numbers Jmax.=76 and were assigned to the 2ν3 band. The very weak 2ν1+ν2 band was recorded and analyzed for the first time. This gave us the possibility to find and analyze, for the first time, the hot band2ν1+ν2-ν2, which is located in the 2200-2380 cm−1 region and totally covered by the strong 2ν1 band. In general, about 1370 transitions were assigned to the bands2ν1+ν2 and 2ν1+ν2-ν2, and 302 ro-vibrational energies of the (2 1 0) state were determined. Ro-vibrational energies obtained from experimental data for both the (0 0 2), and (2 1 0) vibrational states were used in the weighted list square fit of the parameters of the effective Hamiltonian, which takes into account additional interactions with the (1 3 0) and (0 5 0) vibrational states. The set of parameters obtained from the fit reproduces the initial experimental data with accuracies close to experimental uncertainties.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Molecular Spectroscopy
_oScientific Journal
463 _tVol. 318
_v[P. 26-33]
_d2015
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aGromova
_bO. V.
_cphysicist
_cEngineer-Researcher of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1982-
_gOlga Vasilievna
_2stltpush
_3(RuTPU)RU\TPU\pers\34333
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aKrivchikova
_bYu. V.
_cphysicist
_ctechnician Tomsk Polytechnic University
_f1991-
_gYuliya Valerjevna
_2stltpush
_3(RuTPU)RU\TPU\pers\35453
701 1 _aSklyarova
_bE. A.
_cphysicist
_cassociate Professor of Tomsk Polytechnic University, candidate of pedagogical Sciences
_f1972-
_gElena Aleksandrovna
_2stltpush
_3(RuTPU)RU\TPU\pers\34705
701 1 _aButtersack
_bT.
701 1 _aSydow
_bC.
701 1 _aBauerecker
_bZ. (S.) H.
_cphysicist
_cJunior researcher at Tomsk Polytechnic University
_f1960-
_gZigurd (Sigurd) Hermann
_2stltpush
_3(RuTPU)RU\TPU\pers\37573
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bФизико-технический институт (ФТИ)
_bКафедра общей физики (ОФ)
_h136
_2stltpush
_3(RuTPU)RU\TPU\col\18734
801 2 _aRU
_b63413507
_c20171003
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.jms.2015.09.009
942 _cCF