| 000 | 04247nla2a2200481 4500 | ||
|---|---|---|---|
| 001 | 645349 | ||
| 005 | 20231030040649.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\10433 | ||
| 035 | _aRU\TPU\network\10424 | ||
| 090 | _a645349 | ||
| 100 | _a20151216a2015 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 105 | _ay z 100zy | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aThe Choice of Conditions for the Determination of Vanadium, Chromium and Arsenic Concentration in Waters by ICP-MS Using Collision Mode _fI. S. Mazurova, A. A. Khvaschevskaya, N. V. Guseva |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: р. 204-205 (11 tit.)] | ||
| 330 | _aInductively coupled plasma mass spectrometry (ICP-MS) is a popular method for the analysis of waters with various matrices and salinity. One of the difficulties of routine measurements by ICP-MS is spectral interferences conditioned by polyatomic ion formation in the plasma. The detection of the background concentration of such elements as vanadium, chromium and arsenic in natural waters by ICP-MS is complicated because of the polyatomic interferences, having the same mass-to-charge ratio. Thus, the purpose of this article is to determine the optimal rate of helium flow for the effective correction of polyatomic interferences of vanadium, chromium and arsenic and the reduction of their detection limits in Cl-rich waters. This research has been carried out using an inductively coupled plasma mass spectrometer NexION 300D with a universal cell technology (UCT) (PerkinElmer, USA) and three model solutions. For the detection of vanadium, chromium and arsenic content in chloride matrix water by ICP-MS, a collision mode is preferable for polyatomic interference correction. The optimal helium flow rate for this purpose is 2.5 ml/min. Under these conditions, the detection limit of vanadium, chromium and arsenic decreases by order of two. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 0 |
_0(RuTPU)RU\TPU\network\3889 _tProcedia Chemistry |
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| 463 | 0 |
_0(RuTPU)RU\TPU\network\10324 _tVol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015) _oXVI International Scientific Conference dedicated to Professor L.P. Kulyov, 25-29 May 2015, Tomsk, Russia _fNational Research Tomsk Polytechnic University (TPU) ; ed. E. I. Korotkova _v[P. 201-205] _d2015 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aплазма | |
| 610 | 1 | _aспектрометрия | |
| 610 | 1 | _aстолкновения | |
| 610 | 1 | _aванадий | |
| 610 | 1 | _aхром | |
| 610 | 1 | _aмышьяк | |
| 610 | 1 | _aаналитические сигналы | |
| 610 | 1 | _aконцентрация | |
| 610 | 1 | _aводы | |
| 700 | 1 |
_aMazurova _bI. S. _chydrogeologist _cengineer of Tomsk Polytechnic University _f1991- _gIrina Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\33867 |
|
| 701 | 1 |
_aKhvaschevskaya _bA. A. _chydrogeologist _cAssociate Professor of Tomsk Polytechnic University, Candidate of geological and mineralogical sciences _f1969- _gAlbina Anatolievna _2stltpush _3(RuTPU)RU\TPU\pers\30953 |
|
| 701 | 1 |
_aGuseva _bN. V. _chydrogeologist _cAssociate Professor of Tomsk Polytechnic University, Candidate of geological and mineralogical sciences _f1984- _gNatalia Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\32200 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра гидрогеологии, инженерной геологии и гидрогеоэкологии (ГИГЭ) _bНаучно-образовательный центр "Вода" (НОЦ "ВОДА") _bПроблемная научно-исследовательская лаборатория гидрогеохимии (ПНИЛ ГГХ) _h260 _2stltpush _3(RuTPU)RU\TPU\col\19129 |
| 801 | 2 |
_aRU _b63413507 _c20161121 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1016/j.proche.2015.10.032 | |
| 856 | 4 | _uhttp://earchive.tpu.ru/handle/11683/15052 | |
| 942 | _cCF | ||