000 | 02775nlm1a2200397 4500 | ||
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001 | 646426 | ||
005 | 20231030040728.0 | ||
035 | _a(RuTPU)RU\TPU\network\11562 | ||
090 | _a646426 | ||
100 | _a20160229a2016 k y0engy50 ba | ||
101 | 0 | _aeng | |
102 | _aUS | ||
135 | _adrnn ---uucaa | ||
181 | 0 | _ai | |
182 | 0 | _ab | |
200 | 1 |
_aSynthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane _fE. Yu. Semitut [et al.] |
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203 |
_aText _celectronic |
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300 | _aTitle screen | ||
320 | _a[References: p. 25-26 (19 tit.)] | ||
330 | _aReaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions. | ||
333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
461 | _tInorganic Chemistry Communications | ||
463 |
_tVol. 64 _v[P. 23-26] _d2016 |
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610 | 1 | _aэлектронный ресурс | |
610 | 1 | _aтруды учёных ТПУ | |
610 | 1 | _aкристаллические структуры | |
701 | 1 |
_aSemitut _bE. Yu. _cchemist _cresearch engineer at Tomsk Polytechnic University _f1985- _gEvgeny Yurjevich _2stltpush _3(RuTPU)RU\TPU\pers\36264 |
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701 | 1 |
_aKomarov _bV. Yu. _gVladislav Yu. |
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701 | 1 |
_aFilatov _bE. Yu. _gEvgeny Yu. |
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701 | 1 |
_aKuznetsova _bA. S. _corganic chemist _cresearch engineer at Tomsk Polytechnic University _f1988- _gAnastasiya Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\36266 |
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701 | 1 |
_aKhlebnikov _bA. I. _cChemist _cProfessor of Tomsk Polytechnic University _f1963- _gAndrey Ivanovich _2stltpush _3(RuTPU)RU\TPU\pers\33927 |
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701 | 1 |
_aPotapov _bA. S. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1981- _gAndrey Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\33909 |
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712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут физики высоких технологий (ИФВТ) _bКафедра биотехнологии и органической химии (БИОХ) _h6810 _2stltpush _3(RuTPU)RU\TPU\col\18693 |
801 | 2 |
_aRU _b63413507 _c20170321 _gRCR |
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856 | 4 | _uhttp://dx.doi.org/10.1016/j.inoche.2015.12.008 | |
942 | _cCF |