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181 0 _ai
182 0 _ab
200 1 _aSynthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane
_fE. Yu. Semitut [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 25-26 (19 tit.)]
330 _aReaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tInorganic Chemistry Communications
463 _tVol. 64
_v[P. 23-26]
_d2016
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aкристаллические структуры
701 1 _aSemitut
_bE. Yu.
_cchemist
_cresearch engineer at Tomsk Polytechnic University
_f1985-
_gEvgeny Yurjevich
_2stltpush
_3(RuTPU)RU\TPU\pers\36264
701 1 _aKomarov
_bV. Yu.
_gVladislav Yu.
701 1 _aFilatov
_bE. Yu.
_gEvgeny Yu.
701 1 _aKuznetsova
_bA. S.
_corganic chemist
_cresearch engineer at Tomsk Polytechnic University
_f1988-
_gAnastasiya Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\36266
701 1 _aKhlebnikov
_bA. I.
_cChemist
_cProfessor of Tomsk Polytechnic University
_f1963-
_gAndrey Ivanovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33927
701 1 _aPotapov
_bA. S.
_cChemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1981-
_gAndrey Sergeevich
_2stltpush
_3(RuTPU)RU\TPU\pers\33909
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут физики высоких технологий (ИФВТ)
_bКафедра биотехнологии и органической химии (БИОХ)
_h6810
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801 2 _aRU
_b63413507
_c20170321
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.inoche.2015.12.008
942 _cCF